Crystal structures of Bu(4)[PhSbBr(2)Cl] and Bu(4)N[Ph(2)SbBr(2)]

被引:0
|
作者
Sharma, P [1 ]
Rosas, N [1 ]
Toscano, A [1 ]
Hernandez, S [1 ]
Shankar, R [1 ]
Cabrera, A [1 ]
机构
[1] Univ Nacl Autonoma Mexico, INST QUIM, COYOACAN 04510, DF, MEXICO
来源
MAIN GROUP METAL CHEMISTRY | 1996年 / 19卷 / 01期
关键词
D O I
暂无
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
Crystal structures have been determined for Bu(4)N[PhSbClBr(2)] (1) and Bu(4)N[Ph(2)SbBr(2)] (2). In solid (1) the anion exists as a dimer with antimony in a distorted square pyramidal geometry while in (2) the anion exists as a monomeric species and has a see saw structure(pseudo trigonal bipyramidal with one position occupied by a lone pair).
引用
收藏
页码:21 / 27
页数:7
相关论文
共 50 条
  • [41] Crystal structures of two solvates of molybdenum octahedral clusters: (Bu4N)2[Mo6Cl8(O3SC6H4CH3)6]•2CH3CN and (Bu4N)2[Mo6Cl8(O3SC6H4CH3)6]•2CH2Cl2
    Sokolov, M. N.
    Mikhailov, M. A.
    Abramov, P. A.
    Fedin, V. P.
    JOURNAL OF STRUCTURAL CHEMISTRY, 2012, 53 (01) : 197 - 201
  • [42] Reaction of n-butyltin dihydroxy chloride with carboxylic and phosphinic acids:: Crystal structures of the ladder [{Sn(n-Bu)(O2CCHPh2)}3Cl2O2]2 and the unsolvated cluster [{Sn(n-Bu)(O2PPh2)Cl2}{Sn(n-Bu)(O2PPh2)2(OH)}]2
    Nagabrahmanandachari, S
    Hemavathi, C
    Swamy, KCK
    Poojary, DM
    Clearfield, A
    MAIN GROUP METAL CHEMISTRY, 1998, 21 (12): : 789 - 802
  • [43] PREPARATION AND PROPERTIES OF NEW NICKEL BISDITHIOLENE CONDUCTORS, [N-BU4N]0.29[NI(DMBIT)2] AND [N-BU4N]0.59[NI(DMBBIP)2]
    NOH, DY
    MIZUNO, M
    CHOY, JH
    SYNTHETIC METALS, 1993, 56 (01) : 1705 - 1710
  • [44] SYNTHESES AND CRYSTAL-STRUCTURES OF THE 1,3,4-LAMBDA-5-DELTA-4-DIAZAPHOSPHOLES [LI(DME)2P(T-BU)2C(PH)NC(PH)N] AND P(T-BU)2C(HPH)NC(PH)N
    STIEGLITZ, G
    NEUMULLER, B
    DEHNICKE, K
    ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES, 1993, 48 (06): : 730 - 736
  • [45] Spectroscopic studies and crystal structure of tetrabutylammonium trichlorodimethylstannate(IV):: BU4NSnMe2Cl3
    Diasse-Sarr, Aminata
    Barry, Aliou Hamady
    Diop, Libasse
    Toscano, Ruben Alfredo
    Mahieu, Bernard
    COMPTES RENDUS CHIMIE, 2007, 10 (06) : 469 - 472
  • [46] Benzeneselenolates of mercury(II).: Crystal and molecular structures of [Hg(SePh)2] and (Bu4N)[Hg(SePh)3]
    Lang, ES
    Dias, MM
    Abram, U
    Vázquez-López, EM
    ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 2000, 626 (03): : 784 - 788
  • [47] X-ray crystal structures of [NHR3]2[Fe4S4X4] (X = PhS, R = Et or n Bu; X = Cl, R = n Bu): implications for sites of protonation in Fe-S clusters
    Al-Rammahi, Thaer M. M.
    Waddell, Paul G.
    Henderson, Richard A.
    TRANSITION METAL CHEMISTRY, 2016, 41 (05) : 555 - 561
  • [48] REACTIVITY OF ORGANOGALLIUM PEROXIDES - OXIDATION OF PHOSPHINES, PHOSPHITES, AND TRIPHENYLARSINE - X-RAY CRYSTAL-STRUCTURES OF ((T)BU)2GA(O(T)BU)(O=ASPH3), ((T)BU)2GA(MU-O(T)BU)(MU-OO(T)BU)GA((T)BU)2, AND ((T)BU)2GA[(O)P(PH)2CH(O)P(PH)2]
    POWER, MB
    ZILLER, JW
    BARRON, AR
    ORGANOMETALLICS, 1993, 12 (12) : 4908 - 4916
  • [49] GROUP-13 AMIDES - SYNTHESES AND MOLECULAR-STRUCTURES OF [(I-BU)2AL-N(H)MES]2, [(I-BU)AL-N(H)PH(T-BU)2-MU-(CME2CH2)]2, [ME2IN-N(H)PH']2, AND [(I-BU)2AL-N(H)ADA]2
    DILLINGHAM, MDB
    HILL, JB
    LEE, BS
    SCHAUER, SJ
    PENNINGTON, WT
    ROBINSON, GH
    HRNCIR, DC
    JOURNAL OF COORDINATION CHEMISTRY, 1993, 28 (3-4) : 337 - 346
  • [50] Crystal structures and normal coordinate analyses of trans-(n-Bu4N)2 [ReCl4IX], X = NCS, NCSe
    Homolya, L
    Struess, S
    Preetz, W
    ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES, 1999, 54 (06): : 767 - 771