Synthesis, optical properties and singlet oxygen generation of a phthalocyanine derivative containing strong two-photon-absorbing chromophores in the periphery

被引：8
|
作者：
Liu, Zijun [1 ]
Xiong, Xiaoqin [2 ]
Li, Yu [1 ]
Li, Suyue [1 ]
Qin, Jingui [1 ]
机构：
[1] Wuhan Univ, Dept Chem, Wuhan 430072, Peoples R China
[2] Xinyang Normal Univ, Dept Chem & Chem Engn, Xinyang 464000, Henan, Peoples R China
来源：
PHOTOCHEMICAL & PHOTOBIOLOGICAL SCIENCES | 2011年 / 10卷 / 11期
基金：
中国国家自然科学基金;
关键词：
2-PHOTON PHOTOSENSITIZED PRODUCTION; CONJUGATED PORPHYRIN DIMERS; ABSORPTION CROSS-SECTIONS; RESONANCE ENERGY-TRANSFER; ENHANCEMENT; SENSITIZERS; EXCITATION;
D O I：
10.1039/c1pp05166k
中图分类号：
Q5 [生物化学]; Q7 [分子生物学];
学科分类号：
071010 ; 081704 ;
摘要：
A phthalocyanine derivative containing two-photon chromophores which are based on pyrimidine was designed and synthesized. Its light-emission property was studied in detail, and a strong energy transfer from peripheral chromophores to the phthalocyanine core was observed. The compound exhibited strong two-photon absorption responses with a two-photon absorption cross-section up to 1153 GM when irradiated with a picosecond laser in the wavelength range of 800-870 nm, and gave good singlet oxygen generation.
引用
收藏
页码：1804 / 1809
页数：6
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