Crystal structure of sodium perchloratotriacetatoneptunate(V) monohydrate Na3NpO2(OOCCH3)3ClO4 . H2O

被引：4
|
作者：
Charushnikova, IA
Fedoseev, AM
Starikova, ZA
机构：
[1] Russian Acad Sci, Inst Chem Phys, Moscow 117915, Russia
[2] Russian Acad Sci, Inst Organoelement Cpds, Moscow 117813, Russia
来源：
RUSSIAN JOURNAL OF COORDINATION CHEMISTRY | 2005年 / 31卷 / 08期
基金：
俄罗斯基础研究基金会;
关键词：
Acetate; Crystal Structure; Water Molecule; Hexagonal; Oxygen Atom;
D O I：
10.1007/s11173-005-0143-x
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The crystal structure of Na3NpO2(OOCCH3)(3)ClO4 center dot H2O was studied by single-crystal X-ray diffraction method. The structure is composed of the complex anions NpO2(OOCCH3)(3)](2-), perchlorate anions, Na cations, and water molecules. The oxygen environment of Np(V) is a hexagonal bipyramid whose equatorial plane is formed by the oxygen atoms of three acetate ions. In addition to the acetate anions, the structure contains the perchlorate ion whose oxygen atoms, except for one, are included in the coordination environment of Na+ cations.
引用
收藏
页码：603 / 607
页数：5
相关论文
共 50 条
  • [21] CRYSTAL STRUCTURE OF [Eu2（Met）3（Gly）(H2O)3]（ClO4）6
    Zheng Yifan Pan KezhenFujian Institute of Research on the Structure of Matter
    结构化学, 1988, (01) : 9 - 12
  • [22] METHYL PROTON TUNNELING IN THE [CR3O(OOCCH3)6(H2O)3]+ ION - A NEUTRON-SCATTERING STUDY
    BOLLEN, SK
    SAARD, NC
    KARU, E
    WHITE, RP
    CANNON, RD
    JAYASOORIYA, UA
    CARLILE, CJ
    ROBERTSON, ST
    STEIGENBERGER, U
    TOMKINSON, J
    SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY, 1990, 46 (06) : 911 - 915
  • [23] THE CRYSTAL AND MOLECULAR-STRUCTURE OF [RH2(OOCCH3)(HNOOCH3)3-(ME2SO)2].2H2O
    AHSAN, MQ
    BERNAL, I
    BEAR, JL
    INORGANICA CHIMICA ACTA, 1986, 115 (02) : 135 - 139
  • [24] Crystal structure of a double Np(V) ammonium propionate, NH 4[(NpO2)3(C2H5COO) 4(H2O)]·3H2O
    Grigor'ev M.S.
    Antipin M.Yu.
    Krot N.N.
    Radiochemistry, 2006, 48 (1) : 6 - 10
  • [25] Synthesis and Use of [Cd(Detu)2(OOCCH3)2]•H2O as Single Molecule Precursor for Cds Nanoparticles
    Ajibade, Peter A.
    SCIENTIFIC WORLD JOURNAL, 2013,
  • [26] Crystal structure of a Np(V) sesquioxalate, Na4(NpO 2)2(C2O4)3·2H 2O
    Charushnikova I.A.
    Krot N.N.
    Polyakova I.N.
    Radiochemistry, 2007, 49 (2) : 112 - 116
  • [27] THE SYNTHESIS AND CRYSTAL STRUCTURE OF Mo3（μ3-O）-（μ-S）3（μ-OOCCH3）(dtp)3（Py）
    Wang Zhe-Min Zhang Bin Huang Weng Huang Jian-Quan Huang Jin-LingDepartment of Chemistry
    结构化学, 1992, (02) : 127 - 129
  • [28] CRYSTAL-STRUCTURE OF CS4(NPO2)3CL6(NO3)H2O - STRUCTURE OF THE POLYMER WITH NPO2+-NPO2+ CATION INTERACTION
    TOMILIN, SV
    VOLKOV, YF
    MELKAYA, RF
    SPIRYAKOV, VO
    KAPSHUKOV, II
    SOVIET RADIOCHEMISTRY, 1986, 28 (03): : 272 - 278
  • [29] A SINGLE-CRYSTAL FOURIER-TRANSFORM RAMAN-SPECTROSCOPIC STUDY OF [CR3O(OOCCH3)6(H2O)3]CL.5H2O
    BOURKE, JP
    CANNON, RD
    GRINTER, R
    JAYASOORIYA, UA
    SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY, 1993, 49 (5-6) : 685 - 690
  • [30] Crystal structure of silver perchlorate monohydrate, Ag(ClO4)(H2O)
    Wartchow, R.
    Ludwig, W.
    Zeitschrift fuer Kristallographie, 1995, 210 (11):
12345