Dicarbonyl(η5-cyclopentadienyl)[2-(phenylsulfanyl)ethyl]iron(II)

被引：0
|
作者：
Mkhize, Dennis S. [1 ]
Nyamori, Vincent O. [1 ]
Bala, Muhammad D. [1 ]
机构：
[1] Univ KwaZulu Natal, Sch Chem, ZA-4000 Durban, South Africa
来源：
ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE | 2011年 / 67卷
关键词：
ORGANOSULFUR DERIVATIVES; METAL CARBONYLS;
D O I：
10.1107/S160053681101511X
中图分类号：
O7 [晶体学];
学科分类号：
0702 ; 070205 ; 0703 ; 080501 ;
摘要：
The title compound, [Fe(C5H5)(C8H9S)(CO)(2)], is a three-legged piano-stool iron(II) complex that is characterized by a thioethyl-linked phenyl ring and a cyclopentadienyl moiety that occupies the apical coordination site. The two aromatic rings are essentially planar with the same maximum deviation of 0.009 angstrom. The mean planes of the phenyl and cyclopentadienyl rings bisect at an acute angle of 50.08 degrees.
引用
收藏
页码：M644 / U1259
页数：9
相关论文
共 50 条
  • [31] DICARBONYL(ETA(5) CYCLOPENTADIENYL)IRON (II) ETA(1) COMPLEXES OF CARBOHYDRATES
    BOOYSEN, JF
    BREDENKAMP, MW
    HOLZAPFEL, CW
    HETEROCYCLES, 1993, 36 (10) : 2195 - 2202
  • [32] Carbonyl(η5-cyclopentadienyl)(trimethylsilyl isocyanide)(triphenylphosphine)iron(II) trifluoromethanesulfonate dichloromethane hemisolvate
    Nakazawa, H
    Itazaki, M
    Owaribe, M
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2005, 61 : M1172 - M1173
  • [33] Synthesis and characterization of (η5-cyclopentadienyl)(η5-(1-(η5-cyclopentadienyl))-2-phenyl-3-ethyl-1-nickelaindenyl) nickel, a new nickelacyclic analogue of nickelocene
    Buchalski, P
    Pasynkiewicz, S
    Pietrzykowski, A
    Pilka, A
    Suwinska, K
    INORGANIC CHEMISTRY COMMUNICATIONS, 2006, 9 (04) : 375 - 378
  • [34] Redox activation of dicarbonyl(η5-cyclopentadienyl)methyl iron within the cavity of β-cyclodextrin:: carbon monoxide insertion in iron-methyl bond
    Pospísil, L
    Hromadová, M
    Fiedler, JB
    Amatore, C
    Verpeaux, JN
    JOURNAL OF ORGANOMETALLIC CHEMISTRY, 2003, 668 (1-2) : 9 - 16
  • [35] Dicarbonyl(eta(5)-cyclopentadienyl)(2,3-dibromopropanamine-kappa N) iron(II) tetrafluoridoborate
    M'thiruaine, Cyprian M.
    Friedrich, Holger B.
    Changamu, Evans O.
    Fernandes, Manuel A.
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2012, 68 : M932 - +
  • [36] Crystal structures of (η5-C5H4COC6H5)Cr(NO)2(X) (X = Cl, I), and unequivocal assignments of C(2,5) and C(3,4) on the cyclopentadienyl ring of dicarbonyl(η5-cyclopentadienyl)nitrosylchromium, (η5-cyclopentadienyl)halodinitrosylchromium (halo = Cl, Br, I), bis(η5-cyclopentadienyl)iron, and tricarbonyl(η5-cyclopentadienyl)methyltungsten bearing a carbonyl substituent in 13C NMR spectra
    Wang, Yu-Pin
    Tang, Wei-Der
    Hwu, Jin-Mei
    Wu, Jia-Chwen
    Cheng, Hsiu-Yao
    Lin, Tso-Shen
    JOURNAL OF ORGANOMETALLIC CHEMISTRY, 2016, 822 : 228 - 240
  • [37] [η5-1,2-bis(4-nitrophenyl)cyclopentadienyl]-(η5-cyclopentadienyl)iron
    McAdam, CJ
    Robinson, BH
    Simpson, J
    ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2003, 59 : M687 - M689
  • [38] Synthesis and photoactivity of novel cationic photoinitiators: (η6-Diphenylmethane) (η5-cyclopentadienyl) iron hexafluorophosphate and (η6-benzophenone) (η5-cyclopentadienyl) iron hexafluorophosphate
    Wang, Tao
    Li, ZhiQ
    Zhang, Ying
    Lu, Mingb
    PROGRESS IN ORGANIC COATINGS, 2009, 65 (02) : 251 - 256
  • [39] Carbonyl(η5-cyclopentadienyl)(isocyanotriphenyl-borato-κC)(triphenylphosphine-κP)iron(II)
    Nakazawa, H
    Itazaki, M
    Owaribe, M
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2005, 61 : M1166 - M1168
  • [40] Carbonyl(η5-cyclopentadienyl)(3,5-dimethyl-pyridine-κN)(triethylsilyl)iron(II)
    Itazaki, Masumi
    Ueda, Kensuke
    Nakazawa, Hiroshi
    ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2007, 63 : M1312 - M1313
12345