Enzyme-like catalysis by single chain nanoparticles that use transition metal cofactors

被引：13
|
作者：
Xiong, Thao M. [1 ]
Garcia, Edzna S. [1 ]
Chen, Junfeng [1 ]
Zhu, Lingyang [2 ]
Alzona, Ariale J. [1 ]
Zimmerman, Steven C. [1 ]
机构：
[1] Univ Illinois, Dept Chem, Urbana, IL 61801 USA
[2] Univ Illinois, Sch Chem Sci, NMR Lab, Urbana, IL 61801 USA
来源：
CHEMICAL COMMUNICATIONS | 2022年 / 58卷 / 07期
基金：
美国国家科学基金会;
关键词：
POLYMERIC NANOPARTICLES; CLICK REACTIONS; COMPLEX; PROBE;
D O I：
10.1039/d1cc05578j
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
We report a modular approach in which a noncovalently cross-linked single chain nanoparticle (SCNP) selectively binds catalyst "cofactors" and substrates to increase both the catalytic activity of a Cu-catalyzed alkyne-azide cycloaddition reaction and the Ru-catalyzed cleavage of allylcarbamate groups compared to the free catalysts.
引用
收藏
页码：985 / 988
页数：4
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