Influence of diethanol amine (DEOA) on structure-property relationships in molded flexible polyurethane foams

被引:0
|
作者
Kaushiva, BD [1 ]
Wilkes, GL [1 ]
机构
[1] Virginia Polytech Inst & State Univ, Dept Chem Engn, Polymer Mat Interfaces Lab, Blacksburg, VA 24061 USA
关键词
polyurethane; foam; diethanol; amine;
D O I
暂无
中图分类号
TQ [化学工业];
学科分类号
0817 ;
摘要
A series of flexible polyurethane foams with varying concentrations of the crosslinking agent diethanol amine (DEOA) were investigated regarding structure property behavior. FTIR and WAXS analyses showed that DEOA had a disrupting affect on the bidentate hydrogen bonding within the hard domains of the polymer. DMS revealed that DEOA softens the foam in the rubbery region and alters the degree of microphase separation. Annealing treatments were shown to reduce the DEOA influence on microphase separation and some of the softening effect. FTIR was used to show that bidentate hydrogen bonding is enhanced through the annealing of DEOA foams.
引用
收藏
页码:1850 / 1854
页数:5
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