Route to Substituted Furan-2(5H)-ones from cycio-Alkenecarboxylic Acids and Acrylates via C-H Activation

被引：17

作者：

Zhu, You-Quan ^{[1
]}

Han, Ting-Feng ^{[1
]}

He, Jing-Li ^{[1
]}

Li, Man ^{[1
]}

Li, Jun-Xian ^{[1
]}

Zhu, Kun ^{[1
]}

机构：

[1] Nankai Univ, Coll Chem, State Key Lab Elementoorgan Chem, Tianjin 300071, Peoples R China

来源：

JOURNAL OF ORGANIC CHEMISTRY | 2017年 / 82卷 / 16期

基金：

中国国家自然科学基金;

关键词：

CATALYZED CARBONYLATIVE CYCLIZATION; BOND ACTIVATION; PHTHALIDES; CHEMISTRY; ARYLATION; ALDEHYDES; ALCOHOLS; AIR;

D O I：

10.1021/acs.joc.7b01423

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Under rhodium(III) catalysis, four kinds of cycloalkenecarboxylic acids successfully reacted with acrylates via direct activation of the beta-alkenyl C-H bond. The present protocol provides the facile and highly efficient synthesis of substituted furan-2(5H)-ones from readily available starting materials with moderate to good yields. In addition, their possible reaction mechanisms were also discussed.

引用

页码：8598 / 8603

页数：6

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