Neutral guests complexation with calix[4]arenes preorganised by intramolecular McMurry reaction

被引：20
|
作者：
Lhoták, P
Zieba, R
Hromádko, V
Stibor, I
Sykora, J
机构：
[1] Inst Chem Technol, Dept Organ Chem, Prague 16628 6, Czech Republic
[2] ASCR, Inst Chem Proc Fundamentals, Prague 16502 6, Czech Republic
来源：
TETRAHEDRON LETTERS | 2003年 / 44卷 / 24期
关键词：
D O I：
10.1016/S0040-4039(03)00994-8
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
The introduction of two aromatic aldehyde moieties into the lower rim of calix[4]arenes led to the precursors that were intramolecularly bridged in the presence of low-valent titanium agents (the McMurry reaction). These Compounds, preorganised in the cone conformation, represent novel receptors with good complexation ability towards suitable neutral guest molecules both in Solution and in the solid state. The influence of preorganisation and overall rigidity of receptor to the complexation process has been Studied. (C) 2003 Elsevier Science Ltd. All rights reserved.
引用
收藏
页码：4519 / 4522
页数：4
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