Phosphazene Base-Catalyzed Intramolecular Cascade Reactions of Aryl-Substituted Enynes

被引：2

作者：

Tang, Jian-Sheng ^{[1
,2
]}

Xie, Ye-Xiang ^{[1
]}

Wang, Zhi-Qiang ^{[1
]}

Deng, Chen-Liang ^{[1
]}

Li, Jin-Heng ^{[1
]}

机构：

[1] Hunan Normal Univ, Key Lab Chem Biol & Tradit Chinese Med Res, Minist Educ, Changsha 410081, Hunan, Peoples R China

[2] Hunan First Normal Univ, Math & Sci Dept, Changsha 410205, Hunan, Peoples R China

来源：

SYNTHESIS-STUTTGART | 2010年 / 18期

基金：

中国国家自然科学基金;

关键词：

P(4)-t-Bu base; cascade cyclization reaction; 9-aryl-3a,4-dihydronaphtho[2,3-c]furan-1(3H)-one; 3-arylallyl; 3-arylpropiolate; DIELS-ALDER REACTIONS; ORGANIC-SYNTHESIS; DEPROTONATIVE FUNCTIONALIZATION; ARYLNAPHTHALENE LACTONES; AMMONIUM CATIONS; T-BU-P4; BASE; PROTIC MEDIA; CYCLOADDITIONS; CYCLIZATION; POLYAMINOPHOSPHAZENES;

D O I：

10.1055/s-0030-1258172

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A novel method for the synthesis of 9-aryl-3a,4-dihydronaphtho[2,3-c]furan-1(3H)-ones has been developed by P(4)-t-Bu-catalyzed intramolecular cascade reactions of enynes. In the presence of a catalytic amount of phosphazene P(4)-t-Bu base, a variety of 3-arylallyl 3-arylpropiolates underwent the cascade cyclization reaction smoothly in moderate to excellent yields.

引用

页码：3204 / 3210

页数：7

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