Homogeneous catalytic hydroamination of alkynes and allenes with ammonia

被引：318

作者：

Lavallo, Vincent ^{[1
]}

Frey, Guido D. ^{[1
]}

Donnadieu, Bruno ^{[1
]}

Soleilhavoup, Michele ^{[1
]}

Bertrand, Guy ^{[1
]}

机构：

[1] Univ Calif Riverside, Dept Chem, UCR CNRS Joint Res Chem Lab UMI 2957, Riverside, CA 92521 USA

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2008年 / 47卷 / 28期

关键词：

alkynes; ammonia; gold; hydroamination; nitrogen heterocycles;

D O I：

10.1002/anie.200801136

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

(Chemical Equation Presented) A golden ticket to the synthesis of reactive nitrogen-containing compounds, such as imines, enamines, and allyl amines, through the addition of NH3 to unsaturated bonds is the cationic cyclic (alkyl)-(amino)carbene-gold(I) catalyst shown in blue (Dipp=diisopropylphenyl). An ideal initial step for the preparation of simple bulk chemicals, this reaction is also useful for the synthesis of more complex molecules (see examples). © 2008 Wiley-VCH Verlag GmbH & Co. KGaA.

引用

页码：5224 / 5228

页数：5

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