Spectral, magnetic and electrochemical studies of layered manganese oxides with P2 and O2 structure

被引：28
|
作者：
Shaju, KM
Ramanujachary, KV
Lofland, SE
Rao, GVS
Chowdari, BVR [1 ]
机构：
[1] Natl Univ Singapore, Dept Phys, Singapore 119260, Singapore
[2] Rowan Coll, Dept Chem & Phys, Glassboro, NJ 08028 USA
来源：
JOURNAL OF MATERIALS CHEMISTRY | 2003年 / 13卷 / 10期
关键词：
D O I：
10.1039/b301043k
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
X-Ray photoelectron spectroscopy (XPS), infrared spectroscopy and magnetic susceptibility studies were performed on layered O2-phase compounds, Li-2/3(Ni1/3Mn2/3)O-2, Li(2/3)+x(Ni1/3Mn2/3)O-2, Li-2/3(Co0.15Mn0.85)O-2 and Li(2/3)+x(Co0.15Mn0.85)O-2 and their respective P2 phases, Na-2/3(Ni1/3Mn2/3)O-2 and Na-2/3(Co0.15Mn0.85)O-2. The observed electrochemical performance was correlated with the oxidation states of the M ions (M=Mn, Ni, Co). Li(2/3)+x(Ni1/3Mn2/3)O-2 and Li(2/3)+x(Co0.15Mn0.85)O-2 show significant improvement in their first-charge capacity over Li-2/3(Ni1/3Mn2/3)O-2 and Li-2/3(Co0.15Mn0.85)O-2 when used as cathodes vs. Li. Chemical analysis and XPS data indicate that the incorporation of xsimilar to1/3 in the above two compounds is accompanied by the reduction of a corresponding amount of Mn4+ to Mn3+ ions in the lattice. The magnetic moments obtained in the paramagnetic region are in fair agreement with the oxidation state of the ions derived from the XPS data for the Ni-system but show deviations for the Co-system. Below 100 K, weak ferrimagnetic ordering is observed in Li(2/3)+x(Ni1/3Mn2/3)O-2 and Li(2/3)+x(Co0.15Mn0.85)O-2.
引用
收藏
页码：2633 / 2640
页数：8
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