Harnessing noncovalent interaction of chalcogen bond in organocatalysis: From the catalyst point of view

被引：39

作者：

Yan, Weitao ^{[2
]}

Zheng, Mingwen ^{[2
]}

Xu, Chunfa ^{[1
,2
]}

Chen, Fen-Er ^{[1
,2
,3
]}

机构：

[1] Fuzhou Univ, Inst Pharmaceut Sci & Technol, Fuzhou 350108, Peoples R China

[2] Fuzhou Univ, Coll Chem, Fuzhou 350108, Peoples R China

[3] Fudan Univ, Shanghai Engn Ctr Ind Asymmetr Catalysis Chiral Dr, Shanghai 200433, Peoples R China

来源：

GREEN SYNTHESIS AND CATALYSIS | 2021年 / 2卷 / 04期

关键词：

Chalcogen bond; Noncovalent interaction; Organocatalysis; Lewis acid; & sigma; -hole; ASYMMETRIC REACTION; KINETIC RESOLUTION; HALOGEN; POLYFLUOROARENES; DONORS;

D O I：

10.1016/j.gresc.2021.08.002

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The introduction of new interactions into organic transformation is an objective of fundamental importance. Chalcogen bond has emerged as an unconventional type of noncovalent interaction which provides a useful synthetic tool for organocatalysis and has become one of the frontiers in chemistry. This review provides an overview for the recent advances in chalcogen bond catalysis. The current typical types of chalcogen bond donors, mechanistic insights for the organic transformation and future direction of chalcogen bond catalysis are discussed.

引用

页码：329 / 336

页数：8

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