Engineering carbene rearrangements in crystals: From molecular information to solid-state reactivity

被引：122
|
作者：
Garcia-Garibay, MA [1 ]
机构：
[1] Univ Calif Los Angeles, Dept Chem & Biochem, Los Angeles, CA 90095 USA
来源：
ACCOUNTS OF CHEMICAL RESEARCH | 2003年 / 36卷 / 07期
关键词：
D O I：
10.1021/ar970309w
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Although severely restricted, reactions in crystals have delivered some of the most impressive examples of chemical control and provided an ideal medium for detailed mechanistic studies. However, to take full advantage of their potential and avoid their shortcomings, a systematic approach for the reliable design of reaction in crystals is required. To that end, strategies based on structural and energetic information contained at the molecular level have been explored with reactions involving carbene rearrangements.
引用
收藏
页码：491 / 498
页数：8
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