Luminescence characteristics and X-ray crystal structure of [Cd(bipy)3][PF6]2 (bipy=2,2′-bipyridine)

被引：15

作者：

Kundu, N

Mandal, D

Chaudhury, M ^{[1
]}

Tiekink, ERT

机构：

[1] Indian Assoc Cultivat Sci, Dept Inorgan Chem, Kolkata 700032, W Bengal, India

[2] Griffith Univ, Sch Sci, Brisbane, Qld 4111, Australia

来源：

APPLIED ORGANOMETALLIC CHEMISTRY | 2005年 / 19卷 / 12期

关键词：

cadmium(II); 2,2 '-bipyridine; luminescence; crystal structure;

D O I：

10.1002/aoc.996

中图分类号：

O69 [应用化学];

学科分类号：

081704 ;

摘要：

The photoluminescence characteristics of the [Cd(biPY)(3)][PF6](2) complex are reported. A moderately large quantum yield (phi) of 1.07 x 10(-2) is exhibited in acetonitrile solution at 298 K. Crystallography shows the dication to have a distorted octahedral geometry and the crystal structure to be stabilized by C-H-. . . pi and C-H-. . . F interactions. Copyright (c) 2005 John Wiley & Sons, Ltd.

引用

页码：1268 / 1270

页数：3

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