Luminescence characteristics and X-ray crystal structure of [Cd(bipy)3][PF6]2 (bipy=2,2′-bipyridine)

被引：15
|
作者：
Kundu, N
Mandal, D
Chaudhury, M [1 ]
Tiekink, ERT
机构：
[1] Indian Assoc Cultivat Sci, Dept Inorgan Chem, Kolkata 700032, W Bengal, India
[2] Griffith Univ, Sch Sci, Brisbane, Qld 4111, Australia
来源：
APPLIED ORGANOMETALLIC CHEMISTRY | 2005年 / 19卷 / 12期
关键词：
cadmium(II); 2,2 '-bipyridine; luminescence; crystal structure;
D O I：
10.1002/aoc.996
中图分类号：
O69 [应用化学];
学科分类号：
081704 ;
摘要：
The photoluminescence characteristics of the [Cd(biPY)(3)][PF6](2) complex are reported. A moderately large quantum yield (phi) of 1.07 x 10(-2) is exhibited in acetonitrile solution at 298 K. Crystallography shows the dication to have a distorted octahedral geometry and the crystal structure to be stabilized by C-H-. . . pi and C-H-. . . F interactions. Copyright (c) 2005 John Wiley & Sons, Ltd.
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页码：1268 / 1270
页数：3
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