New insights into structural and electrochemical properties of anisotropic polymer electrolytes

被引：21

作者：

Livshits, E

Kovarsky, R

Lavie, N

Hayashi, Y

Golodnitsky, D ^{[1
]}

Peled, E

机构：

[1] Tel Aviv Univ, Sch Chem, IL-69978 Tel Aviv, Israel

[2] Wolfson Appl Mat Res Ctr, IL-69978 Tel Aviv, Israel

[3] Hebrew Univ Jerusalem, Dept Appl Phys, IL-91904 Jerusalem, Israel

来源：

ELECTROCHIMICA ACTA | 2005年 / 50卷 / 19期

关键词：

polymer electrolyte; conduction properties; magnetic field;

D O I：

10.1016/j.electacta.2005.02.047

中图分类号：

O646 [电化学、电解、磁化学];

学科分类号：

081704 ;

摘要：

The inter-relationship between the orthogonal alignment of polymer helices and improvement of lithium-transport properties of polymer electrolytes has been determined by scanning electron microscopy, differential-scanning calorimetry and dielectric spectroscopy. It is suggested that ordering of the polymer electrolyte accompanied by increased conduction properties is achieved by mutual coordination of local dipole moments of the polar CH2-CH2-O units during casting under a magnetic field. (c) 2005 Elsevier Ltd. All rights reserved.

引用

页码：3805 / 3814

页数：10

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