Synthesis of [Ca2(Co1-xCux)2O4]yCoO2 single crystals and their intrinsic properties

被引：0

作者：

Suzuki, M ^{[1
]}

Horii, S ^{[1
]}

Sano, M ^{[1
]}

Fujie, K ^{[1
]}

Otzschi, K ^{[1
]}

Shimoyama, J ^{[1
]}

Kishio, K ^{[1
]}

机构：

[1] Univ Tokyo, Dept Superconduct, Bunkyo Ku, Tokyo 1138656, Japan

来源：

SOLID-STATE CHEMISTRY OF INORGANIC MATERIALS IV | 2003年 / 755卷

关键词：

D O I：

暂无

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Thin plate-like [Ca-2(Co1-xCux)(2)O-4](y)CoO2 single crystals were successfully grown by the flux method using SrCl2 solvent. The largest crystal size was approximately 3 x 3 x 0.01 mm(3). The copper concentrations, x, in the crystals were found to be depending on each crystal, suggesting a certain solid-solution range of copper in the present system. The obtained crystal showed low resistivity (similar to4.3mOmegacm) and high Seebeck coefficient (similar to160muVK(-1)) at 300K. The crystal showed anisotropic magnetization with larger magnetization under H//c. Irreversible magnetization behavior below similar to90K was also found under H//c.

引用

页码：375 / 380

页数：6

共 50 条

[21] Intrinsic Josephson properties in (Hg, Re)Ba2Ca3Cu4O10+δ single crystals
Ueda, S.
Okutsu, T.
Kubo, Y.
Ishii, S.
Tsuda, S.
Yamaguchi, T.
Horii, S.
Shimoyama, J.
Kishio, K.
Takano, Y.
PHYSICA C-SUPERCONDUCTIVITY AND ITS APPLICATIONS, 2008, 468 (15-20): : 1925 - 1928
[22] Synthesis and physical properties of NaxCo2O4 single crystals
Tang, XF
Abbott, E
Kolis, JK
Aaron, K
Tritt, TM
ICT: 2005 24th International Conference on Thermoelectrics, 2005, : 484 - 487
[23] Synthesis and thermoelectric properties of NaxCo2O4 single crystals
Tang, Xiaofeng
Aaron, Kelvin
Abbott, Edward
Kolis, Joseph W.
Tritt, Terry M.
MATERIALS AND TECHNOLOGIES FOR DIRECT THERMAL-TO-ELECTRIC ENERGY CONVERSION, 2006, 886 : 81 - +
[24] Intrinsic properties of the Mott insulator Ca2RuO4+δ (δ=0) studied with single crystals
Fukazawa, H
Nakatsuji, S
Maeno, Y
PHYSICA B, 2000, 281 : 613 - 614
[25] Co2+-Cu2+ substitution in bieberite solid-solution series, (Co1-xCux)SO4.7H2O,0.00≤x≤0.46:: Synthesis, single-crystal structure analysis, and optical spectroscopy
Redhammer, Gunther J.
Koll, Lisa
Bernroider, Manfred
Tippelt, Gerold
Amthauer, Georg
Roth, Georg
AMERICAN MINERALOGIST, 2007, 92 (04) : 532 - 545
[26] Effect of synthesis on the magnetostrictive properties of CoFe 2O4 spinel ferrite
Karpova T.S.
Vasilyev V.G.
Vladimirova E.V.
Nosov A.P.
Bulletin of the Russian Academy of Sciences: Physics, 2011, 75 (8) : 1036 - 1038
[27] THE HYPERFINE FIELDS ON AL-27 NUCLEI IN (CO1-XCUX)2MNAL ALLOYS
STETSENKO, PN
SURIKOV, VV
POKATILOV, VS
LASKIN, AI
AVKSENTJEV, YI
VESTNIK MOSKOVSKOGO UNIVERSITETA SERIYA 3 FIZIKA ASTRONOMIYA, 1986, 27 (04): : 104 - 105
[28] Influence of the cation substitution on the magnetic properties of LiCo2O4 and Li(Me,Co)2O4 spinels
Peña, O
Bodenez, V
Guizouarn, T
Meza, E
Gautier, JL
BOLETIN DE LA SOCIEDAD ESPANOLA DE CERAMICA Y VIDRIO, 2004, 43 (04): : 736 - 739
[29] Structural and intrinsic Josephson properties of Bi2Sr2Ca1-yYyCu2O8+δ single crystal
Yamaki, K.
Murata, K.
Irie, A.
PHYSICA C-SUPERCONDUCTIVITY AND ITS APPLICATIONS, 2016, 529 : 40 - 43
[30] PREPARATION AND PROPERTIES OF CA2V2O7 SINGLE-CRYSTALS
DELEPREVIER, AFG
BUCHANAN, RC
JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1982, 129 (11) : 2562 - 2565

← 1 2 3 4 5 →