On the Enhancement of Molecular Hydrogen Interactions in Nanoporous Solids for Improved Hydrogen Storage

被引:29
|
作者
Klontzas, Emmanouel [1 ]
Tylianakis, Emmanuel [2 ]
Froudakis, George E. [1 ]
机构
[1] Univ Crete, Dept Chem, Iraklion 71003, Crete, Greece
[2] Univ Crete, Dept Mat Sci & Technol, Iraklion 71003, Crete, Greece
来源
关键词
METAL-ORGANIC FRAMEWORKS; DOPED CARBON NANOTUBES; AB-INITIO; BINDING STRENGTH; H-2; STORAGE; 1ST-PRINCIPLES; ADSORPTION; CAPACITY; CENTERS;
D O I
10.1021/jz2005368
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The need for a transition toward sustainable and environmentally friendly energy sources seems to be very important nowadays. Hydrogen is being investigated as an alternative choice to fossil fuels for future transportation needs. In the past few years, significant progress has been made in storing sufficient amounts of hydrogen in porous materials. In particular, nanostructured materials can bind H-2 with adequate strength required for adsorptive storage. In this Perspective, an analysis of the types of interactions between molecular hydrogen and the host material is performed, supported by illustrative examples from the literature. Guidelines for the enhancement of hydrogen interaction with the material's pore structure and novel directions for designing materials with higher storage performance are proposed.
引用
收藏
页码:1824 / 1830
页数:7
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