A convenient one-pot synthesis of 1,2-azaphospholanium salts

被引：10

作者：

Aladzheva, IM ^{[1
]}

Lobanov, DI ^{[1
]}

Bykhovskaya, OV ^{[1
]}

Petrovskii, PV ^{[1
]}

Lyssenko, KA ^{[1
]}

Mastryukova, TA ^{[1
]}

机构：

[1] Russian Acad Sci, AN Nesmeyanov Organoelement Cpds Inst, Moscow 119991, Russia

来源：

HETEROATOM CHEMISTRY | 2003年 / 14卷 / 07期

关键词：

D O I：

10.1002/hc.10209

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A novel facile one-pot synthesis of the 1,2-azaphospholanes by intramolecular alkylation of 3-halopropyl amides of tricoordinate phosphorus has been suggested. Using this method, a series of the differently N-substituted 1,2-azaphospholanium salts were synthesized. 3-Aminopropylphosphine oxides were obtained by hydrolysis of the salts. A probable mechanism of the 1,2-azaphospholanium salts formation is discussed. (C) 2003 Wiley Periodicals, Inc.

引用

页码：596 / 602

页数：7

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