Blue-light-promoted carbon-carbon double bond isomerization and its application in the syntheses of quinolines

被引：41

作者：

Chen, Xinzheng ^{[1
]}

Qiu, Shuxian ^{[1
]}

Wang, Sasa ^{[1
]}

Wang, Huifei ^{[1
]}

Zhai, Hongbin ^{[1
,2
,3
]}

机构：

[1] Peking Univ, Shenzhen Grad Sch, Key Lab Chem Genom, Guangdong Prov Key Lab Nanomicro Mat Res, Shenzhen 518055, Peoples R China

[2] Lanzhou Univ, Coll Chem & Chem Engn, State Key Lab Appl Organ Chem, Lanzhou 730000, Peoples R China

[3] Collaborat Innovat Ctr Chem Sci & Engn Tianjin, Tianjin 300071, Peoples R China

来源：

ORGANIC & BIOMOLECULAR CHEMISTRY | 2017年 / 15卷 / 30期

关键词：

CIS-TRANS ISOMERIZATION; STEREOSELECTIVE-SYNTHESIS; PHOTOCHEMICAL-REACTIONS; ALKENE ISOMERIZATION; COUPLING REACTION; METAL-COMPLEXES; OLEFINATION; EFFICIENT; MECHANISM; PHOTOISOMERIZATION;

D O I：

10.1039/c7ob00558j

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A blue-light-promoted carbon-carbon double bond isomerization in the absence of any photoredox catalyst is reported. It provides rapid access to a series of quinolines in good to excellent yields under simple aerobic conditions. The protocol is direct, catalyst-free and operationally convenient.

引用

页码：6349 / 6352

页数：4

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