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Blue-light-promoted carbon-carbon double bond isomerization and its application in the syntheses of quinolines
被引:41
|作者:
Chen, Xinzheng
[1
]
Qiu, Shuxian
[1
]
Wang, Sasa
[1
]
Wang, Huifei
[1
]
Zhai, Hongbin
[1
,2
,3
]
机构:
[1] Peking Univ, Shenzhen Grad Sch, Key Lab Chem Genom, Guangdong Prov Key Lab Nanomicro Mat Res, Shenzhen 518055, Peoples R China
[2] Lanzhou Univ, Coll Chem & Chem Engn, State Key Lab Appl Organ Chem, Lanzhou 730000, Peoples R China
[3] Collaborat Innovat Ctr Chem Sci & Engn Tianjin, Tianjin 300071, Peoples R China
关键词:
CIS-TRANS ISOMERIZATION;
STEREOSELECTIVE-SYNTHESIS;
PHOTOCHEMICAL-REACTIONS;
ALKENE ISOMERIZATION;
COUPLING REACTION;
METAL-COMPLEXES;
OLEFINATION;
EFFICIENT;
MECHANISM;
PHOTOISOMERIZATION;
D O I:
10.1039/c7ob00558j
中图分类号:
O62 [有机化学];
学科分类号:
070303 ;
081704 ;
摘要:
A blue-light-promoted carbon-carbon double bond isomerization in the absence of any photoredox catalyst is reported. It provides rapid access to a series of quinolines in good to excellent yields under simple aerobic conditions. The protocol is direct, catalyst-free and operationally convenient.
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页码:6349 / 6352
页数:4
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