Blue-light-promoted carbon-carbon double bond isomerization and its application in the syntheses of quinolines

被引:41
|
作者
Chen, Xinzheng [1 ]
Qiu, Shuxian [1 ]
Wang, Sasa [1 ]
Wang, Huifei [1 ]
Zhai, Hongbin [1 ,2 ,3 ]
机构
[1] Peking Univ, Shenzhen Grad Sch, Key Lab Chem Genom, Guangdong Prov Key Lab Nanomicro Mat Res, Shenzhen 518055, Peoples R China
[2] Lanzhou Univ, Coll Chem & Chem Engn, State Key Lab Appl Organ Chem, Lanzhou 730000, Peoples R China
[3] Collaborat Innovat Ctr Chem Sci & Engn Tianjin, Tianjin 300071, Peoples R China
关键词
CIS-TRANS ISOMERIZATION; STEREOSELECTIVE-SYNTHESIS; PHOTOCHEMICAL-REACTIONS; ALKENE ISOMERIZATION; COUPLING REACTION; METAL-COMPLEXES; OLEFINATION; EFFICIENT; MECHANISM; PHOTOISOMERIZATION;
D O I
10.1039/c7ob00558j
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
A blue-light-promoted carbon-carbon double bond isomerization in the absence of any photoredox catalyst is reported. It provides rapid access to a series of quinolines in good to excellent yields under simple aerobic conditions. The protocol is direct, catalyst-free and operationally convenient.
引用
收藏
页码:6349 / 6352
页数:4
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