CuI-catalyzed direct synthesis of diaryl thioethers from aryl boronic acids and arylsulfonyl chlorides

被引：15

作者：

Huang, Keke ^{[1
]}

Yang, Min ^{[2
]}

Lai, Xiao-Jing ^{[1
]}

Hu, Xin ^{[2
]}

Qiu, Guanyinsheng ^{[3
]}

Liu, Jin-Biao ^{[1
]}

机构：

[1] Jiangxi Univ Sci & Technol, Sch Met & Chem Engn, 86 Hongqi Rd, Ganzhou 341000, Peoples R China

[2] Gannan Med Univ, Dept Forens Sci, 1 Yixueyuan Rd, Ganzhou 341000, Jiangxi, Peoples R China

[3] Jiaxing Univ, Coll Biol Chem Sci & Engn, 118 Jiahang Rd, Jiaxing 314001, Peoples R China

来源：

APPLIED ORGANOMETALLIC CHEMISTRY | 2020年 / 34卷 / 02期

关键词：

aryl boronic acid; arylsulfonyl chloride; Cu(I) catalysis; thioether; C-H BOND; CROSS-COUPLINGS; SULFONYL CHLORIDES; HIGHLY EFFICIENT; S BOND; NICKEL-CATALYST; N-OXIDES; TE BOND; SULFUR; SULFENYLATION;

D O I：

10.1002/aoc.5385

中图分类号：

O69 [应用化学];

学科分类号：

081704 ;

摘要：

A CuI-catalyzed direct coupling of aryl boronic acids with arylsulfonyl chlorides for the preparation of diaryl thioethers was developed. The reaction is initiated by a PPh3 reduction of the arylsulfonyl chloride, followed by a CuI-catalyzed C-S coupling with an aryl boronic acid. Various arylsulfonyl chlorides can directly serve as a sulfur source in this mild and efficient reaction giving the desired products in moderate to good yields. Moreover, this practical method has also been applied to the thioetherification of aryl iodides and acetylacetones.

引用

页数：9

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