pH value controlled structures: from macrocyclic complex monomer to 2D macrocyclic sheet

被引:12
|
作者
Ou, GC [1 ]
Su, CY [1 ]
Yao, JH [1 ]
Lu, TB [1 ]
机构
[1] Sun Yat Sen Univ, Sch Chem & Chem Engn, Instrumentat Anal & Res Ctr, Guangzhou 510275, Peoples R China
基金
中国国家自然科学基金;
关键词
macrocyclic complex monomer; 2D sheet; reversibly converted;
D O I
10.1016/j.inoche.2005.01.030
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
By changing the pH value, the macrocyclic complex monomer [CuL(H2O)(2)] center dot 6H(2)O, 1 center dot 6H(2)O, (L = 3,10-bis(2-butyrate)-1,3,5,8,10,12-hexaazacyclo-tetradecane) and its 2D sheet {[CuH2L](ClO4)(2)}(m) 2, can be reversibly converted. (c) 2005 Elsevier B.V. All rights reserved.
引用
收藏
页码:421 / 424
页数:4
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