Excess enthalpy, density, and speed of sound for the mixtures.8-pinene+2-methyl-1-propanol or 2-methyl-2-propanol at several temperatures

被引:23
|
作者
Langa, Elisa [1 ]
Mainar, Ana M. [1 ]
Pardo, Juan I. [1 ]
Urieta, Jos S. [1 ]
机构
[1] Univ Zaragoza, Aragon Inst Engn Res, Fac Ciencias, Grp Appl Thermodynam & Surf, E-50009 Zaragoza, Spain
来源
关键词
D O I
10.1021/je700193w
中图分类号
O414.1 [热力学];
学科分类号
摘要
Excess enthalpies, densities, and speeds of sound are reported for the binary mixtures beta-pinene + 2-methyl-1-propanol at the temperatures (283.15, 298.15, 303.15, 313.15, and 323.15) K and beta-pinene + 2-methyl-2-propanol at the temperatures (303.15, 313.15, and 323.15) K. Excess molar volumes have been calculated from the densities and speed of sound deviations, isentropic compressibilities, and excess isentropic compressibilities from speeds of sound. The excess properties and deviations of properties have been fitted to Pade approximants. Excess molar enthalpies and excess molar volumes are positive for both mixtures, whereas speed of sound deviations show both positive and negative values. Also, positive and negative values of excess isentropic compressibility are observed for the mixture beta-pinene + 2-methy-1-propanol, but the mixture beta-pinene + 2-methyl-2-propanol exhibits positive values only. The excess properties are compared with those of the mixtures of beta-pinene with 1-butanol and 2-butanol.
引用
收藏
页码:2182 / 2187
页数:6
相关论文
共 50 条
  • [41] Temperature dependence of surface tension of 2-methyl-1-propanol and 2-methyl-2-propanol+n-hexane mixtures
    Giner, Beatriz
    Bandres, Isabel
    Giner, Ignacio
    Montano, Diego F.
    Lopez, M. Carmen
    PHYSICS AND CHEMISTRY OF LIQUIDS, 2008, 46 (06) : 643 - 652
  • [42] Phase equilibria in the systems 2-methyl-2-propanol plus methyl 1,1-dimethylpropyl ether and 2-methylpentane+2-methyl-2-propanol plus methyl 1,1-dimethylpropy ether
    Loras, S
    Aucejo, A
    Muñoz, R
    Ordoñez, LM
    JOURNAL OF CHEMICAL AND ENGINEERING DATA, 1999, 44 (06): : 1163 - 1168
  • [43] Isothermal Vapor-Liquid Equilibrium of Ternary Mixtures Containing 2-Methyl-1-propanol or 2-Methyl-2-propanol, n-Hexane, and 1-Chlorobutane at 298.15 K
    Guerrero, Hernando
    Giner, Ignacio
    Artigas, Hector
    Lafuente, Carlos
    Gascon, Ignacio
    JOURNAL OF CHEMICAL AND ENGINEERING DATA, 2010, 55 (02): : 739 - 744
  • [44] Solubility of Anthracene in Ternary Cyclohexane plus Propanol+2-Methyl-1-propanol and Cyclohexane plus Butanol+2-Methyl-1-propanol Mixtures
    Proctor, Amy
    Blake-Taylor, Brooke H.
    Acree, William E., Jr.
    JOURNAL OF CHEMICAL AND ENGINEERING DATA, 2008, 53 (12): : 2910 - 2912
  • [45] Viscosity of Water plus tert-Butyl Alcohol (2-Methyl-2-propanol) Mixtures at Low Temperatures and High Pressure
    Harris, Kenneth R.
    Woolf, Lawrence A.
    JOURNAL OF CHEMICAL AND ENGINEERING DATA, 2009, 54 (02): : 581 - 588
  • [46] HIGH-PRESSURE PHASE-EQUILIBRIA FOR CARBON-DIOXIDE 2-METHYL-2-PROPANOL AND CARBON-DIOXIDE 2-METHYL-2-PROPANOL WATER - MEASUREMENT AND PREDICTION
    KIM, JS
    YOON, JH
    LEE, H
    FLUID PHASE EQUILIBRIA, 1994, 101 : 237 - 245
  • [47] Vapor-liquid equilibria at 101.3 kPa for binary mixtures containing 2-methyl-1-propanol+2-methyl-1-butanol, 2-methyl-1-propanol+3-methyl-1-butanol, and 2-methyl-1-propanol+1-pentanol
    Resa, Jose M.
    Goenaga, Jose M.
    Iglesias, Miguel
    JOURNAL OF CHEMICAL AND ENGINEERING DATA, 2006, 51 (05): : 1892 - 1895
  • [48] Vapor pressures at several temperatures between 278.15 and 323.15 K and excess functions at T=298.15 K for 1-bromobutane with 1-butanol or 2-methyl-2-propanol
    Garriga, R
    Martínez, S
    Pérez, P
    Gracia, M
    JOURNAL OF CHEMICAL AND ENGINEERING DATA, 2002, 47 (02): : 322 - 328
  • [49] EXCESS VOLUMES AND SPEED OF SOUND FOR M-CHLOROTOLUENE PLUS 2-PROPANOL, PLUS 2-METHYL-1-PROPANOL, AND PLUS 3-METHYL-1-BUTANOL AT 303.15-K
    SREENIVASULU, B
    NAIDU, PR
    JOURNAL OF CHEMICAL AND ENGINEERING DATA, 1993, 38 (04): : 622 - 624
  • [50] Measurements for the Dissociation Conditions of Methane Hydrate in the Presence of 2-Methyl-2-propanol
    Kuo, Ping-Chen
    Chen, Li-Jen
    Lin, Shiang-Tai
    Chen, Yan-Ping
    JOURNAL OF CHEMICAL AND ENGINEERING DATA, 2010, 55 (11): : 5036 - 5039