Reactions of dinuclear carboxylate ruthenium (I) complexes with alcohols.: The unexpected oxidation of primary alcohols to carboxylic ligands

被引：1
|
作者：
Soler, J [1 ]
Moldes, I [1 ]
de la Encarnación, E [1 ]
Ros, J [1 ]
机构：
[1] Univ Autonoma Barcelona, Dept Quim, E-08193 Barcelona, Spain
来源：
JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1999年 / 580卷 / 01期
关键词：
ruthenium; carboxylate; formate; alkoxide;
D O I：
10.1016/S0022-328X(98)01131-0
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The dinuclear ruthenium (I) complexes [Ru-2(HCO2)(2)(CO)(4)(PPh3)(2)] react with primary alcohols R'CH2OH in refluxing toluene, giving rise to [Ru-2(R'CO2)(2)(CO)(4)(PPh3)(2)] compounds. Other carboxylate bridging complexes react with alcohols R " OH to give very unstable alkoxide compounds [Ru-2(R " O)(2)(CO)(4)(PPh3)(2)]. (C) 1999 Elsevier Science S.A. All rights reserved.
引用
收藏
页码：108 / 109
页数：2
相关论文
共 50 条
  • [31] Amination of aliphatic alcohols with urea catalyzed by ruthenium complexes: effect of supporting ligands
    Dindar, Sara
    Nemati Kharat, Ali
    JOURNAL OF COORDINATION CHEMISTRY, 2020, 73 (13) : 1954 - 1966
  • [32] Ruthenium complexes of electronically coupled cyclopentadienone ligands catalysts for transformations of propargyl alcohols
    Haak, Edgar
    EUROPEAN JOURNAL OF ORGANIC CHEMISTRY, 2007, 2007 (17) : 2815 - 2824
  • [33] Dehydrogenation of primary alcohols to carboxylic acids in water catalyzed by PNHN-manganese(I) carbonyl complexes
    Fu, Dexin
    Wang, Zheng
    Liu, Ming
    Liu, Song
    Wang, Yizhou
    Wei, Chunyan
    Ma, Yanping
    Liu, Qingbin
    Solan, Gregory A.
    Sun, Wen-Hua
    JOURNAL OF CATALYSIS, 2024, 436
  • [34] Fine-tuning NHC ligands for ruthenium-catalyzed hydrogenation of carboxylic esters to alcohols
    Kadyrov, Renat
    JOURNAL OF CATALYSIS, 2023, 426 : 173 - 177
  • [35] A NOVEL DINUCLEAR RUTHENIUM-1,8-NAPHTHYRIDINE CATALYST FOR THE OXIDATION OF ALCOHOLS AND THE EPOXIDATION OF ALKENES
    BOELRIJK, AEM
    VANVELZEN, MM
    NEENAN, TX
    REEDIJK, J
    KOOIJMAN, H
    SPEK, AL
    JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1995, (23) : 2465 - 2467
  • [36] Aerobic oxidation of primary alcohols catalyzed by copper complexes of 1,10-phenanthroline-derived ligands
    Das, Oindrila
    Paine, Tapan Kanti
    DALTON TRANSACTIONS, 2012, 41 (37) : 11476 - 11481
  • [37] REACTIONS OF ALCOHOLS WITH DIOLEFINS CATALYZED BY COPPER(I) AND RHODIUM(I) COMPLEXES
    TAYLOR, BW
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 1972, : 53 - &
  • [38] Oxidation and β-Alkylation of Alcohols Catalysed by Iridium(I) Complexes with Functionalised N-Heterocyclic Carbene Ligands
    Victoria Jimenez, M.
    Fernandez-Tornos, Javier
    Javier Modrego, F.
    Perez-Torrente, Jesus J.
    Oro, Luis A.
    CHEMISTRY-A EUROPEAN JOURNAL, 2015, 21 (49) : 17877 - 17889
  • [39] Homogeneous Photocatalytic Oxidation of Alcohols by a Chromophore-Catalyst Dyad of Ruthenium Complexes
    Chen, Weizhong
    Rein, Francisca N.
    Rocha, Reginaldo C.
    ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2009, 48 (51) : 9672 - 9675
  • [40] Carbon-carbon bond fission on oxidation of primary alcohols to carboxylic acids
    Bekish, Andrei V.
    TETRAHEDRON LETTERS, 2012, 53 (24) : 3082 - 3085
12345