Selective formation of a two-dimensional coordination polymer based on a tridentate phospholane ligand and gold(I)

被引：8

作者：

Hoy, Reinhard ^{[1
]}

Loennecke, Peter ^{[1
]}

Hey-Hawkins, Evamarie ^{[1
]}

机构：

[1] Univ Leipzig, Inst Inorgan Chem, Fac Chem & Mineral, D-04103 Leipzig, Germany

来源：

DALTON TRANSACTIONS | 2018年 / 47卷 / 41期

关键词：

CRYSTAL-STRUCTURE; COMPLEXES; LUMINESCENT; AU; 3-COORDINATE; AU(I); AG; TETRAHEDRA; PHOSPHINES; CHEMISTRY;

D O I：

10.1039/c8dt03630f

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The tridentate phosphine ligand 1,3,5-tris[(E)-(4-phospholano-2,6-diethyl)styryl]benzene (1) reacts with [AuCl(tht)] (tht = tetrahydrothiophene) independent of the stoichiometry employed with selective formation of a two-dimensional coordination polymer (ratio 1 : 1) with the gold(I) cations in a trigonal-planar [3 + 1] coordination geometry. Each of the three coordinating phosphine units originates from another ligand, thus forming a polymeric structure.

引用

页码：14515 / 14520

页数：6

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