Methyl to alkylidene migration within trans-[WMe(=CHPh)(CO)(2)(eta-C5H5)]

被引：7

作者：

Muir, JE ^{[1
]}

Haynes, A ^{[1
]}

Winter, MJ ^{[1
]}

机构：

[1] UNIV SHEFFIELD,DEPT CHEM,SHEFFIELD S3 7HF,S YORKSHIRE,ENGLAND

来源：

CHEMICAL COMMUNICATIONS | 1996年 / 15期

关键词：

D O I：

10.1039/cc9960001765

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Treatment of the anionic carbene complex [W(=CHPh>(CO)(2)(eta-C5H5)](-) with MeI affords a complex trans-[WMe(=CHPh)(CO)(2)(eta-C5H5)] which isomerises by means of an intramolecular methyl to carbene migration to afford the eta(3)-benzyl complex [W{eta(3)-CH(Me)C(6)H5}(CO)(2)(eta-C5H5)].

引用

页码：1765 / 1766

页数：2

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