Ultrafast dynamics of mesoionic liquid solutions studied with incoherent light

被引:16
|
作者
Menezes, LD
de Araújo, CB [1 ]
Alencar, MARC
Athayde, PF
Miller, J
Simas, AM
机构
[1] Univ Fed Pernambuco, Dept Fis, BR-50670901 Recife, PE, Brazil
[2] Univ Fed Pernambuco, Dept Quim Fundamental, BR-50670901 Recife, PE, Brazil
[3] Univ Fed Rural Pernambuco, Dept Quim, BR-52171030 Recife, PE, Brazil
[4] Univ Fed Paraiba, Dept Quim, BR-58051970 Joao Pessoa, Paraiba, Brazil
[5] Univ Fed Paraiba, Lab Tecnol Farmaceut, BR-58051970 Joao Pessoa, Paraiba, Brazil
关键词
D O I
10.1016/S0009-2614(01)01014-4
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Optical Kerr shutter (OKS) measurements were performed in a solution of a mesoionic compound (MIC) in dimethylsulfoxide using 10 ns pulses of broadband noisy light with a coherence time of 160 fs. The results show a light induced birefringence with two main components: an instantaneous one, which follows the laser coherence time, and a sub-picosecond component, with a characteristic time of 560 fs, which is attributed to the birefringence decay due to molecular interactions. (C) 2001 Elsevier Science B.V. All rights reserved.
引用
收藏
页码:163 / 166
页数:4
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