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Palladium-Catalyzed Three-Component Coupling Reaction of Allyl Carboxylates, Norbornenes and Diboronates Involving Sequential Olefins Insertion and Borylation Reaction
被引:11
|作者:
Li, Zun
[1
]
Zheng, Jia
[1
]
Li, Chunsheng
[1
]
Wu, Wanqing
[1
]
Jiang, Huanfeng
[1
]
机构:
[1] South China Univ Technol, Sch Chem & Chem Engn, Key Lab Funct Mol Engn Guangdong Prov, Guangzhou 510640, Guangdong, Peoples R China
基金:
中国国家自然科学基金;
关键词:
FUNCTIONALIZED ALLYLBORONIC ACIDS;
H BOND FUNCTIONALIZATION;
CO-POLYMERIZATION;
DERIVATIVES;
COMPLEXES;
ESTERS;
NORBORNADIENE;
CYCLIZATION;
EFFICIENT;
ACETATES;
D O I:
10.1002/cjoc.201800536
中图分类号:
O6 [化学];
学科分类号:
0703 ;
摘要:
The Summary of main observation and conclusion An efficient Pd-catalyzed three-component coupling reaction of allyl carboxylates, norbornenes and diboronates is described, which allows efficient assembly of C(sp(3))-C(sp(3)) and C(sp(3))-B bonds in a single process. Moreover, this approach shows advantages of good chemo- and regioselectivity, as well as good substrates suitability.
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页码:140 / 147
页数:8
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