Palladium-Catalyzed Three-Component Coupling Reaction of Allyl Carboxylates, Norbornenes and Diboronates Involving Sequential Olefins Insertion and Borylation Reaction

被引:11
|
作者
Li, Zun [1 ]
Zheng, Jia [1 ]
Li, Chunsheng [1 ]
Wu, Wanqing [1 ]
Jiang, Huanfeng [1 ]
机构
[1] South China Univ Technol, Sch Chem & Chem Engn, Key Lab Funct Mol Engn Guangdong Prov, Guangzhou 510640, Guangdong, Peoples R China
基金
中国国家自然科学基金;
关键词
FUNCTIONALIZED ALLYLBORONIC ACIDS; H BOND FUNCTIONALIZATION; CO-POLYMERIZATION; DERIVATIVES; COMPLEXES; ESTERS; NORBORNADIENE; CYCLIZATION; EFFICIENT; ACETATES;
D O I
10.1002/cjoc.201800536
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The Summary of main observation and conclusion An efficient Pd-catalyzed three-component coupling reaction of allyl carboxylates, norbornenes and diboronates is described, which allows efficient assembly of C(sp(3))-C(sp(3)) and C(sp(3))-B bonds in a single process. Moreover, this approach shows advantages of good chemo- and regioselectivity, as well as good substrates suitability.
引用
收藏
页码:140 / 147
页数:8
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