Lewis Acid Catalyzed Inverse Electron-Demand Diels-Alder Reaction of 1,2-Diazines

被引：95
|
作者：
Kessler, Simon N. [1 ]
Wegner, Hermann A. [1 ]
机构：
[1] Univ Basel, Dept Chem, CH-4056 Basel, Switzerland
来源：
ORGANIC LETTERS | 2010年 / 12卷 / 18期
基金：
瑞士国家科学基金会;
关键词：
HETEROCYCLIC AZADIENES; BASIS-SETS; 1,2,4-TRIAZINES; ENAMINES; ATOMS;
D O I：
10.1021/ol101701z
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
A systematic approach toward Lewis acid catalyzed inverse electron-demand Diels-Alder (IEDDA) reactions of 1,2-diazines is described. The general concept is first investigated by DFT calculations, supported by spectroscopic data, and finally proven in the experiment.
引用
收藏
页码：4062 / 4065
页数：4
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