Synthesis, photophysical and electrochemical properties of 1-aminoperylene bisimides

被引:38
|
作者
Chen, Kew-Yu [1 ]
Fang, Tzu-Chien [1 ]
Chang, Ming-Jen [1 ]
机构
[1] Feng Chia Univ, Dept Chem Engn, Taichung 40724, Taiwan
关键词
1-Aminoperylene bisimides; Intramolecular charge transfer; Purple dyes; Self-assembly; SOLUBLE PERYLENE DERIVATIVES; SOLAR-CELLS; ORGANIC SEMICONDUCTORS; BUILDING-BLOCKS; ENERGY-TRANSFER; DIIMIDES; TRANSISTORS; ELECTRON; DYES; CHROMOPHORES;
D O I
10.1016/j.dyepig.2011.06.023
中图分类号
O69 [应用化学];
学科分类号
081704 ;
摘要
1-Aminoperylene bisimides (1a-1c) were synthesized under mild condition in high yields, and were characterized by FT-IR, (1)H NMR, UV-Vis, HRMS spectra, cyclic voltammetry, differential scanning calorimetry, and thermogravimetric analyses. These compounds are stable up to 310 degrees C according to thermogravimetric analyses. They undergo two quasi-reversible one-electron oxidations and two quasi-reversible one-electron reductions in dichloromethane at modest potentials. Their spectroscopic properties in various conditions and complementary density functional theory (DFT) calculations are reported. (C) 2011 Elsevier Ltd. All rights reserved.
引用
收藏
页码:517 / 523
页数:7
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