The formation of neptunium peroxo complexes upon reduction of neptunium(VI) by hydrogen peroxide in concentrated solutions of alkalis

被引：0

作者：

Shilov, VP ^{[1
]}

Gogolev, AV ^{[1
]}

Pikaev, AE ^{[1
]}

机构：

[1] Russian Acad Sci, Inst Phys Chem, Moscow 117915, Russia

来源：

MENDELEEV COMMUNICATIONS | 1998年 / 06期

关键词：

D O I：

暂无

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Kinetic studies have shown that the formation of Np-V peroxo complexes upon reduction of Np-VI by hydrogen peroxide in concentrated solutions of alkalis occurs via the intermediate appearance of Np-VI peroxo complexes.

引用

页码：220 / 222

页数：3

共 32 条

[21] FORMATION OF PEROXO OXALATO COMPLEX OF TUNGSTEN(VI) DIRECTLY FROM TUNGSTEN CARBIDE AND HYDROGEN-PEROXIDE - A NEW PATH TO THE TOTAL SYNTHESIS OF THE ORGANIC-COMPOUND
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MATSUMOTO, K
INORGANICA CHIMICA ACTA, 1987, 133 (02) : 201 - 203
[22] REACTION OF HYDROGEN-PEROXIDE WITH METAL-COMPLEXES .4. KINETIC-STUDIES ON THE PEROXO COMPLEX-FORMATION OF (POLYAMINOPOLYCARBOXYLATO)DIOXOVANADATE(V)
FUNAHASHI, S
MIDORIKAWA, T
TANAKA, M
INORGANIC CHEMISTRY, 1980, 19 (01) : 91 - 97
[23] Nucleation of silver upon the reduction by hydrogen in aqueous polyphosphate-containing solutions: Formation of clusters and nanoparticles
B. G. Ershov
E. V. Abkhalimov
Colloid Journal, 2007, 69 : 579 - 584
[24] Nucleation of silver upon the reduction by hydrogen in aqueous polyphosphate-containing solutions: Formation of clusters and nanoparticles
Ershov, B. G.
Abkhalimov, E. V.
COLLOID JOURNAL, 2007, 69 (05) : 579 - 584
[25] KINETICS AND MECHANISM OF HYDROGEN-PEROXIDE REACTIONS OF DIPEROXO(AMINE)CHROMIUM(IV) COMPLEXES - EVIDENCE FOR FORMATION OF AN OXODIPEROXOCHROMIUM(VI) INTERMEDIATE
RANGANATHAN, CK
RAMASAMI, T
RAMASWAMY, D
SANTAPPA, M
INORGANIC CHEMISTRY, 1989, 28 (07) : 1306 - 1310
[26] RESONANCE RAMAN STUDIES OF TRANSITION-METAL PEROXO COMPLEXES .3. THE BLUE INTERMEDIATE FORMED IN THE REACTION OF CHROMIUM(VI) WITH HYDROGEN-PEROXIDE IN STRONGLY ACID-SOLUTION
HESTER, RE
NOUR, EM
JOURNAL OF RAMAN SPECTROSCOPY, 1981, 11 (01) : 39 - 42
[27] REACTIONS OF HYDROGEN-PEROXIDE WITH METAL-COMPLEXES .3. THERMODYNAMIC AND KINETIC STUDIES ON FORMATION, DISSOCIATION, AND DECOMPOSITION OF PEROXOCHROMIUM(VI) COMPLEXES IN ACID-MEDIA
FUNAHASHI, S
UCHIDA, F
TANAKA, M
INORGANIC CHEMISTRY, 1978, 17 (10) : 2784 - 2789
[28] REACTIONS OF HYDROGEN-PEROXIDE WITH METAL-COMPLEXES .2. KINETIC STUDIES ON PEROXO COMPLEX-FORMATION OF NITRILOTRIACETATODIOXOVANADATE(V) AND DIOXO(2,6-PYRIDINEDICARBOXYLATO)VANADTE(V)
FUNAHASHI, S
HARAGUCHI, K
TANAKA, M
INORGANIC CHEMISTRY, 1977, 16 (06) : 1349 - 1353
[29] REACTIONS OF HYDROGEN-PEROXIDE WITH METAL-COMPLEXES .5. MECHANISM OF THE PEROXO COMPLEX-FORMATION OF "(NITRILOTRIACETATO)DIOXOVANADATE(V) AS STUDIED BY A HIGH-PRESSURE STOPPED-FLOW TECHNIQUE
FUNAHASHI, S
ISHIHARA, K
TANAKA, M
INORGANIC CHEMISTRY, 1981, 20 (01) : 55 - 51
[30] HYDROGEN PEROXIDE FORMATION UPON OXIDATION OF OXALIC ACID IN PRESENCE AND ABSENCE OF OXYGEN AND OF MANGANESE(II) .1. MANGANESE(VII), CERRIUM(IV), CHROMIUM(VI), AND COBALT(III) AS OXIDANTS
KOLTHOFF, IM
MEEHAN, EJ
KIMURA, M
JOURNAL OF PHYSICAL CHEMISTRY, 1971, 75 (21): : 3343 - &

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