The formation of neptunium peroxo complexes upon reduction of neptunium(VI) by hydrogen peroxide in concentrated solutions of alkalis

被引：0
|
作者：
Shilov, VP [1 ]
Gogolev, AV [1 ]
Pikaev, AE [1 ]
机构：
[1] Russian Acad Sci, Inst Phys Chem, Moscow 117915, Russia
来源：
MENDELEEV COMMUNICATIONS | 1998年 / 06期
关键词：
D O I：
暂无
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Kinetic studies have shown that the formation of Np-V peroxo complexes upon reduction of Np-VI by hydrogen peroxide in concentrated solutions of alkalis occurs via the intermediate appearance of Np-VI peroxo complexes.
引用
收藏
页码：220 / 222
页数：3
相关论文
共 32 条
  • [1] A KINETIC STUDY OF THE REDUCTION OF NEPTUNIUM (VI) BY HYDROGEN PEROXIDE
    ZIELEN, AJ
    SULLIVAN, JC
    COHEN, D
    HINDMAN, JC
    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1958, 80 (21) : 5632 - 5635
  • [2] The formation of a neptunium(V) peroxo complex upon gamma-radiolysis of aqueous alkaline solutions of neptunium ions
    Gogolev, AV
    Shilov, VP
    Pikaev, AK
    MENDELEEV COMMUNICATIONS, 1996, (04) : 127 - 128
  • [3] REDUCTION OF NEPTUNIUM(VI) AND NEPTUNIUM-(V) BY HYDRAZINE ON SOLID CATALYSTS IN NITRIC-ACID SOLUTIONS
    TANANAEV, IG
    SHILOV, VP
    DZYUBENKO, VI
    SOVIET RADIOCHEMISTRY, 1989, 31 (06): : 674 - 678
  • [4] Reduction of neptunium(V) and uranium(VI) with iron(II) in bicarbonate solutions
    Gogolev A.V.
    Zakharova E.V.
    Rodygina N.I.
    Fedoseev A.M.
    Shilov V.P.
    Radiochemistry, 2006, 48 (3) : 249 - 253
  • [5] KINETICS OF REDUCTION OF PLUTONIUM(VI) AND NEPTUNIUM(VI) BY SULFIDE IN NEUTRAL AND ALKALINE-SOLUTIONS
    NASH, KL
    CLEVELAND, JM
    SULLIVAN, JC
    WOODS, M
    INORGANIC CHEMISTRY, 1986, 25 (08) : 1169 - 1173
  • [6] REDUCTION OF NEPTUNIUM(V) BY HYDROGEN-PEROXIDE IN THE PRESENCE OF OXALIC-ACID
    MALKOVA, NN
    MATYUKHA, VA
    AFANASEVA, TV
    KROT, NN
    SOVIET RADIOCHEMISTRY, 1986, 28 (03): : 294 - 300
  • [7] EPR spectroscopic studies on the formation of chromium(V) peroxo complexes in the reaction of chromium(VI) with hydrogen peroxide
    Zhang, LB
    Lay, PA
    INORGANIC CHEMISTRY, 1998, 37 (08) : 1729 - 1733
  • [8] RADIOLYTIC REDUCTION OF PU(VI) AND OXIDATION OF PU(IV) IN THE PRESENCE OF NEPTUNIUM IN HNO3 SOLUTIONS
    VLADIMIROVA, MV
    KULIKOV, IA
    SOSNOVSKII, OA
    NIKISHOVA, LK
    SOVIET RADIOCHEMISTRY, 1983, 24 (03): : 267 - 276
  • [9] Plutonium(IV) peroxide formation in nitric medium and kinetics Pu(VI) reduction by hydrogen peroxide
    Maillard, C
    Adnet, JM
    RADIOCHIMICA ACTA, 2001, 89 (08) : 485 - 490
  • [10] A valence control method based on a Pt-aided hydrogen peroxide treatment for yielding tetravalent neptunium and plutonium in nitric acid solutions
    Suh, Moo Yul
    Lee, Chang Heon
    Song, Byoung Chul
    Lee, Myung Ho
    Han, Sun Ho
    Sohn, Se Chul
    Jee, Kwang Yong
    BULLETIN OF THE KOREAN CHEMICAL SOCIETY, 2008, 29 (02): : 475 - 478
1234