Rearrangement of a tricyclic 2,5-cyclohexadienone: Towards a general synthetic route to the daphnanes and (+)-resiniferatoxin

被引：0
|
作者：
Jackson, SR [1 ]
Johnson, MG [1 ]
Mikami, M [1 ]
Shiokawa, S [1 ]
Carreira, EM [1 ]
机构：
[1] ETH Zentrum, Organ Chem Lab, CH-8092 Zurich, Switzerland
来源：
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2001年 / 40卷 / 14期
关键词：
D O I：
10.1002/1521-3773(20010716)40:14<2694::AID-ANIE2694>3.0.CO;2-D
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Light as a reagent: A highly functionalized structure that serves as a daphnane template can be formed by the photorearrangement of a 2,5-cyclohexadienone subunit within a complex tricyclic ring system (see scheme). The chemistry we describe should not only find use in the total synthesis of resiniferatoxin and related daphnanes, but should also provide useful templates for access to complex analogues.
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页码：2694 / 2697
页数：4
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