Reduction of N2 to ammonia and hydrazine utilizing H2 as the reductant

被引：89

作者：

Gilbertson, JD ^{[1
]}

Szymczak, NK ^{[1
]}

Tyler, DR ^{[1
]}

机构：

[1] Univ Oregon, Dept Chem, Eugene, OR 97403 USA

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2005年 / 127卷 / 29期

关键词：

D O I：

10.1021/ja053030g

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The trans-Fe(DMeOPrPE)2Cl2 complex (where DMeOPrPE = 1,2-bis(bis(methoxypropyl)phosphino)ethane) undergoes a series of reactions that involve the activation of both H2 and N2 to produce ammonia and hydrazine. A Leigh-type cycle was employed to achieve laboratory fixation of dinitrogen at room temperature and pressure utilizing H2 as the reductant. Copyright © 2005 American Chemical Society.

引用

页码：10184 / 10185

页数：2

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