Metal-hydride hydrogen atom transfer (MHAT) reactions in natural product synthesis

被引：52

作者：

Wu, Jinghua ^{[1
]}

Ma, Zhiqiang ^{[1
]}

机构：

[1] South China Univ Technol, Sch Chem & Chem Engn, Key Lab Funct Mol Engn Guangdong Prov, Wushan Rd 381, Guangzhou 510641, Peoples R China

来源：

ORGANIC CHEMISTRY FRONTIERS | 2021年 / 8卷 / 24期

基金：

中国国家自然科学基金;

关键词：

OXIDATION-REDUCTION HYDRATION; ASYMMETRIC TOTAL-SYNTHESIS; DIVERGENT TOTAL SYNTHESES; CATALYZED HYDROHYDRAZINATION; UNACTIVATED OLEFINS; MOLECULAR-OXYGEN; MN; HYDROAZIDATION; PHENYLSILANE; VINBLASTINE;

D O I：

10.1039/d1qo01139a

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The metal-hydride hydrogen atom transfer (MHAT) reaction plays an important role in the field of natural product synthesis. MHAT, as a powerful method, has been employed by chemists to construct C-C, C-H, and C-heteroatom bonds. In this review, we summarize the recent total synthesis of natural products using MHAT to functionalize olefins with first-row transition metal catalysts such as cobalt, manganese and iron.

引用

页码：7050 / 7076

页数：27

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