Metal-hydride hydrogen atom transfer (MHAT) reactions in natural product synthesis

被引：52
|
作者：
Wu, Jinghua [1 ]
Ma, Zhiqiang [1 ]
机构：
[1] South China Univ Technol, Sch Chem & Chem Engn, Key Lab Funct Mol Engn Guangdong Prov, Wushan Rd 381, Guangzhou 510641, Peoples R China
来源：
ORGANIC CHEMISTRY FRONTIERS | 2021年 / 8卷 / 24期
基金：
中国国家自然科学基金;
关键词：
OXIDATION-REDUCTION HYDRATION; ASYMMETRIC TOTAL-SYNTHESIS; DIVERGENT TOTAL SYNTHESES; CATALYZED HYDROHYDRAZINATION; UNACTIVATED OLEFINS; MOLECULAR-OXYGEN; MN; HYDROAZIDATION; PHENYLSILANE; VINBLASTINE;
D O I：
10.1039/d1qo01139a
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
The metal-hydride hydrogen atom transfer (MHAT) reaction plays an important role in the field of natural product synthesis. MHAT, as a powerful method, has been employed by chemists to construct C-C, C-H, and C-heteroatom bonds. In this review, we summarize the recent total synthesis of natural products using MHAT to functionalize olefins with first-row transition metal catalysts such as cobalt, manganese and iron.
引用
收藏
页码：7050 / 7076
页数：27
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