Structure and magnetic ordering of KxH1-xNi(OH2)4[Ru2(CO3)4]•zH2O

被引：25
|
作者：
Kennon, Bretni S.
Her, Jae-Hyuk
Stephens, Peter W. [1 ]
Shum, William W.
Miller, Joel S.
机构：
[1] SUNY Stony Brook, Dept Phys & Astron, Stony Brook, NY 11794 USA
[2] Univ Utah, Dept Chem, Salt Lake City, UT 84112 USA
来源：
INORGANIC CHEMISTRY | 2007年 / 46卷 / 22期
关键词：
D O I：
10.1021/ic701318q
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
KxH1-xNi(OH2)(4)[Ru-2(CO3)(4)]center dot zH(2)O is a ferrimagnet (T-c = 4.3 K) formed from the reaction of K-3[Ru(II/III)2(CO3)(4)] and Ni-II in water. It possesses a new 3-D network structural motif composed of linked chains and mu(3)-CO3 linkages to both Ru and Ni sites. Each Ni(II) bonds to four oxygens and to two [Ru-2(CO3)(4)](3-) moieties in a cis manner, and four mu(3)-CO3 groups from each [Ru-2(CO3)(4)](3-) have two oxygens bonding to the Ru-2 moiety, forming the typical paddle-wheel core, and trans pairs of the third CO32- oxygen axially bonded to either another Ru-2 or Ni-ll.
引用
收藏
页码：9033 / 9035
页数：3
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