Structure and magnetic ordering of KxH1-xNi(OH2)4[Ru2(CO3)4]•zH2O

被引：25
|
作者：
Kennon, Bretni S.
Her, Jae-Hyuk
Stephens, Peter W. [1 ]
Shum, William W.
Miller, Joel S.
机构：
[1] SUNY Stony Brook, Dept Phys & Astron, Stony Brook, NY 11794 USA
[2] Univ Utah, Dept Chem, Salt Lake City, UT 84112 USA
来源：
INORGANIC CHEMISTRY | 2007年 / 46卷 / 22期
关键词：
D O I：
10.1021/ic701318q
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
KxH1-xNi(OH2)(4)[Ru-2(CO3)(4)]center dot zH(2)O is a ferrimagnet (T-c = 4.3 K) formed from the reaction of K-3[Ru(II/III)2(CO3)(4)] and Ni-II in water. It possesses a new 3-D network structural motif composed of linked chains and mu(3)-CO3 linkages to both Ru and Ni sites. Each Ni(II) bonds to four oxygens and to two [Ru-2(CO3)(4)](3-) moieties in a cis manner, and four mu(3)-CO3 groups from each [Ru-2(CO3)(4)](3-) have two oxygens bonding to the Ru-2 moiety, forming the typical paddle-wheel core, and trans pairs of the third CO32- oxygen axially bonded to either another Ru-2 or Ni-ll.
引用
收藏
页码：9033 / 9035
页数：3
相关论文
共 50 条
  • [1] Structure and magnetic properties of LnIII[Ru2(CO3)4] • 8H2O
    Her, Jae-Hyuk
    Kennon, Bretni S.
    Shum, William W.
    Stephens, Peter W.
    Miller, Joel S.
    INORGANICA CHIMICA ACTA, 2008, 361 (12-13) : 3462 - 3464
  • [2] Spin glass ordering in heterometallic carbonates with pillared layer structure: K4[Mn(H2O)4{Ru2(CO3)4}2]•4H2O
    Jia, Yan-Yan
    Chang, Zhu-Guo
    Yang, Jian-Hui
    Liu, Bin
    INORGANICA CHIMICA ACTA, 2015, 424 : 162 - 166
  • [3] A diruthenium soft ferromagnet showing Tc=3.0 K: Mn4(H2O)16H[Ru2(CO3)4]2[Ru2(CO3)4(H2O)2]•11H2O
    Liu, Bin
    Jin, Jin
    Liu, Xue-Mei
    Hu, Huai-Ming
    Ding, Tuo
    Zhang, Na
    Jia, Yan-Yan
    Xue, Gang-Lin
    DALTON TRANSACTIONS, 2012, 41 (16) : 4748 - 4750
  • [4] Preparation and structure of Ru2(μ-O2CCF3)2(CO)4(NCMe)2
    Bruce, MI
    Skelton, BW
    White, AH
    Zaitseva, NN
    AUSTRALIAN JOURNAL OF CHEMISTRY, 1999, 52 (06) : 621 - 623
  • [5] AN INVESTIGATION OF THE BONDING IN [RU2(O2CCF3)4] AND [RU2(O2CCF3)4(NO)2]
    CLARK, DL
    GREEN, JC
    REDFERN, CM
    JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1989, (06): : 1037 - 1044
  • [6] Nature of Magnetic Ordering in Molecular Magnet Mn[Fe(CN)6]2/3•zH2O
    Thakur, Nidhi
    Yusuf, S. M.
    Yakhmi, J. V.
    INTERNATIONAL CONFERENCE ON MAGNETIC MATERIALS (ICMM-2010), 2010, 1347 : 145 - 148
  • [7] THE CRYSTAL-STRUCTURE OF NA2H2[CO4I3O18(OH2)6]-[CO4I3O16(OH)2(OH2)6].22H2O
    KONDO, H
    KOBAYASHI, A
    SASAKI, Y
    BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, 1982, 55 (07) : 2113 - 2117
  • [8] AN EXPERIMENTAL AND THEORETICAL-STUDY OF THE IONIZATION ENERGIES OF RU2(O2CCF3)4 AND RU2(O2CCF3)4(NO)2
    CLARK, DL
    GREEN, JC
    REDFERN, CM
    QUELCH, GE
    HILLIER, IH
    GUEST, MF
    CHEMICAL PHYSICS LETTERS, 1989, 154 (04) : 326 - 329
  • [9] Structural and magnetic effects of mechanically grinding Co3(OH)2(C4O4)2•3H2O
    McNeely, James Halley
    Falaneh, Khwaila
    Ganegoda, Hasitha
    Clark, Ronald
    Segre, Carlo
    Cage, Brant
    POLYHEDRON, 2014, 79 : 60 - 65
  • [10] Tetra- and hexanuclear cage molecules based on diruthenium tetracarbonyl sawhorse units:: Synthesis and molecular structure of [{Ru2(CO)4(PPh3)2}2(O2CCH2CO2)2] and [{Ru2(CO)4(PMe3)2}3(O2CC6H4CO2)3]
    Auzias, Mathieu
    Therrien, Bruno
    Siiss-Fink, Georg
    INORGANIC CHEMISTRY COMMUNICATIONS, 2007, 10 (12) : 1420 - 1424
12345