Genesis and Metallogenic Characteristics of the Zhunsujihua Granitic Intrusions in Sonid Left Banner, Inner Mongolia, China

The Zhunsujihua porphyry Mo-Cu deposit is located in the Erenhot-East Ujimqin metallogenic belt in northeastern China. Granodioritic intrusions in the mining area are dominated by granodiorite and granodiorite porphyry, but the Mo mineralization is limited within the granodiorite. Zircon LA-ICP-MS U-Pb dating yields crystallization ages of 301.5 +/- 3.0 Ma for granodiorite and 296.0 +/- 3.0 Ma for granodiorite porphyry. These ages constrain the magmatic activity at the Zhunsujihua deposit that took place during the subduction of the Paleo-Asian oceanic plate. Whole-rock geochemical data suggest that the granodioritic intrusions belong to calc-alkaline and high-K calc-alkaline series, and are characterized by enrichment in K, Rb, U, Th, and Pb, and depletion in Nb, Ta, Ti, and P. The negative Eu, Ba, and Sr anomalies suggest that they have experienced extensive fractionation of plagioclase. Trace element compositions of zircons from the Zhunsujihua deposit provide constraints on the oxygen fugacity (integral O-2) of the magma, which is shown to high values with increment Delta FMQ = +0.5 to +5.6. The wide range of zircon epsilon(Hf) (t) (+1.3 similar to+9.4) values, positive whole-rock epsilon(Nd) (t) (+2.5 similar to+3.9) values, and relatively low initial (Sr-87/Sr-86)(i) (0.70367 similar to 0.70561) ratios indicate that the magmas mainly originated from a juvenile lower crust source derived from depleted mantle, but mixed with pre-existing crustal components. Moreover, the juvenile lower crust represents the main source of Mo for the Zhunsujihua deposit. A high magmatic oxygen fugacity and fractional crystallization played key roles in forming the Zhunsujihua deposit.