A high-capacity hexaazatrinaphthylene anode for aqueous organic hybrid flow batteries

被引：19
|
作者：
Liu, Zirui [1 ]
Wang, Zheng [1 ]
Shi, Yanjun [1 ]
Shen, Yong-Miao [2 ]
Wang, Wenchang [1 ]
Chen, Zhidong [1 ]
Xu, Juan [1 ]
Cao, Jianyu [1 ]
机构：
[1] Changzhou Univ, Jiangsu Key Lab Adv Catalyt Mat & Technol, Changzhou 213164, Jiangsu, Peoples R China
[2] Zhejiang Sci Tech Univ, Dept Chem, Hangzhou 310018, Peoples R China
来源：
JOURNAL OF MATERIALS CHEMISTRY A | 2021年 / 9卷 / 47期
基金：
中国国家自然科学基金;
关键词：
DENSITY;
D O I：
10.1039/d1ta06138k
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
By using a microwave assisted Schiff-base condensation reaction between triquinoyl and 1,2-diaminobenzene, we synthesize a water-insoluble fused phenazine derivative, hexaazatrinaphtylene (HATN), and study its electrochemical performance against a K-4[Fe(CN)(6)]/K-3[Fe(CN)(6)] catholyte in an alkaline aqueous hybrid flow battery. Reversible two-step three-electron transfers and rapid surface-controlled redox reaction kinetics are observed for the HATN electrode in alkaline aqueous solution. Compared to previously reported organic anode materials for aqueous hybrid flow batteries, HATN exhibits greatly enhanced specific capacity and comparable efficiency and cycling stability.
引用
收藏
页码：27028 / 27033
页数：6
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