Synthesis of a novel sandwich copper complex [(TACN)2CU](ClO4)2•H2O

被引：0
|
作者：
Hu, NL [1 ]
Dong, HZ [1 ]
Huang, ZX [1 ]
Xie, FX [1 ]
机构：
[1] Anhui Univ, Dept Chem, Hefei 230039, Peoples R China
来源：
ASIAN JOURNAL OF CHEMISTRY | 2005年 / 17卷 / 02期
关键词：
copper(II) complex; triazacyclononane; sandwich structure;
D O I：
暂无
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A novel sandwiched copper(II) complex with the ligand 1,4,7-triazacyclononane has been synthesized and characterized by using X ray diffraction analysis. The results indicate that its crystallographic structure is monoclinic, possessing parameters; P2(1)/c, a = 9.5896(3) angstrom, b = 13.5820(10) angstrom, c = 9.5850(3) angstrom, alpha = 90.00 degrees, beta = 119.3850(10)degrees, gamma = 90.00 degrees, nu = 1087.79(5) angstrom(3), Z = 2, Dx = 1,627 mg cm(-3), R = 0.0560, omega R = 0.1548, F(000) = 550.
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收藏
页码：1276 / 1280
页数：5
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