Synthesis of a novel sandwich copper complex [(TACN)2CU](ClO4)2•H2O

被引：0
|
作者：
Hu, NL [1 ]
Dong, HZ [1 ]
Huang, ZX [1 ]
Xie, FX [1 ]
机构：
[1] Anhui Univ, Dept Chem, Hefei 230039, Peoples R China
来源：
ASIAN JOURNAL OF CHEMISTRY | 2005年 / 17卷 / 02期
关键词：
copper(II) complex; triazacyclononane; sandwich structure;
D O I：
暂无
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A novel sandwiched copper(II) complex with the ligand 1,4,7-triazacyclononane has been synthesized and characterized by using X ray diffraction analysis. The results indicate that its crystallographic structure is monoclinic, possessing parameters; P2(1)/c, a = 9.5896(3) angstrom, b = 13.5820(10) angstrom, c = 9.5850(3) angstrom, alpha = 90.00 degrees, beta = 119.3850(10)degrees, gamma = 90.00 degrees, nu = 1087.79(5) angstrom(3), Z = 2, Dx = 1,627 mg cm(-3), R = 0.0560, omega R = 0.1548, F(000) = 550.
引用
收藏
页码：1276 / 1280
页数：5
相关论文
共 50 条
  • [1] Synthesis and Crystal Structure of a Novel Complex [Cu（Phen）3]（ClO4）2（btio）(H2O)
    ZHANG Chen-Xia LIU Zhan-Quanb LIAO Dai-Zhengb JIANG Zong-Huib
    结构化学, 2004, (03) : 247 - 251
  • [2] Synthesis and crystal structure of a novel complex [Cu(Phen)3](ClO4)2(btio)(H2O)
    Zhang, CX
    Liu, ZQ
    Liao, DZ
    Jiang, ZH
    Yan, SP
    CHINESE JOURNAL OF STRUCTURAL CHEMISTRY, 2004, 23 (03) : 247 - 251
  • [3] Synthesis and Crystal Structure of a New Tetracopper Complex [Cu(H2O)3Cu(HCDTA)]2(ClO4)2•H2O
    Wang Mei-Xiang
    Dang Zhen-Hua
    Xu Li
    CHINESE JOURNAL OF STRUCTURAL CHEMISTRY, 2010, 29 (04) : 551 - 554
  • [4] Synthesis and Crystal Structure of a New Tetracopper Complex [Cu(H2O)3Cu(HCDTA)]2(ClO4)2·H2O
    王美香
    党振华
    徐立
    结构化学, 2010, 29 (04) : 551 - 554
  • [5] STRUCTURAL VARIATIONS IN MACROCYCLIC COPPER(II) COMPLEXES - CRYSTAL AND MOLECULAR-STRUCTURES OF [CU(CYCLOPS)H2O](CLO4) AND [CU(PREH)H2O](CLO4).H2O
    ANDERSON, OP
    PACKARD, AB
    INORGANIC CHEMISTRY, 1979, 18 (07) : 1940 - 1947
  • [6] Synthesis, crystal structure, and magnetic properties of hexanuclear heterometal complex {[CO(Dien)(Npda)]2Cu(H2O)}2(ClO4)4•8H2O
    Polyakova, IN
    Sergienko, VS
    Poznyak, AL
    Ellert, OG
    ZHURNAL NEORGANICHESKOI KHIMII, 1997, 42 (10): : 1653 - 1659
  • [7] Synthesis, characterization and crystal structure of a binuclear Copper (II) complex [Cu(II)2(Paba)2(4, 4′-Bipy) (H2O)2]·(ClO4)2
    Ouyang, Miao
    Cai, Cheng-Xiang
    Zhao, Zhi-Yuan
    Chen, Qian-Qian
    Jiang, Yi-Min
    Rengong Jingti Xuebao/Journal of Synthetic Crystals, 2009, 38 (03): : 710 - 714
  • [8] CRYSTAL STRUCTURE OF A NOVEL BINUCLEAR COPPER COMPLEX WITH DIACETYLDIOXIME, Cu2(C4H7N2O2)3(H2O)(ClO4).
    Lin, S.
    Liu, S. -X.
    ACTA CRYSTALLOGRAPHICA A-FOUNDATION AND ADVANCES, 1999, 55 : 415 - 415
  • [9] Synthesis and crystal structure of Cu(phen) (H2O)2 • ClO4(phen = phenanthroline)
    Jian, FF
    Liu, GY
    Hao, QL
    Wang, X
    CHINESE JOURNAL OF INORGANIC CHEMISTRY, 2003, 19 (04) : 419 - 422
  • [10] Crystal structure of the binuclear copper(II) complex [Cu2(tacn)2(μ-ox)](ClO4)2 (tacn = 1,4,7-triazacyclononane)
    Zhang, L
    Yan, HL
    Yan, SP
    Jiang, ZH
    Liao, DZ
    Wang, GL
    POLISH JOURNAL OF CHEMISTRY, 1999, 73 (02) : 391 - 394
12345