Chiral thioether-based catalysts in asymmetric synthesis: recent advances

被引：67

作者：

Gomez Arrayas, Ramon ^{[1
]}

Carretero, Juan C. ^{[1
]}

机构：

[1] Univ Autonoma Madrid, Dept Quim Organ, E-28049 Madrid, Spain

来源：

CHEMICAL COMMUNICATIONS | 2011年 / 47卷 / 08期

关键词：

ENANTIOSELECTIVE 1,3-DIPOLAR CYCLOADDITION; MIXED PHOSPHORUS/SULFUR LIGANDS; STABILIZED SULFUR YLIDES; DIRECT MANNICH REACTION; AZOMETHINE YLIDES; ALLYLIC SUBSTITUTIONS; SULFONIUM SALTS; DERIVATIVES; MECHANISM; IMINES;

D O I：

10.1039/c0cc03978k

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Chiral, non-racemic, thioethers have provided organic chemists with useful tools for developing new reagents and catalysts for practical modern asymmetric synthesis. Disclosed herein is a brief personal overview on major recent contributions in this field in which the sulfur atom plays a leading role in the reaction pathway.

引用

页码：2207 / 2211

页数：5

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