Chiral thioether-based catalysts in asymmetric synthesis: recent advances

被引：67
|
作者：
Gomez Arrayas, Ramon [1 ]
Carretero, Juan C. [1 ]
机构：
[1] Univ Autonoma Madrid, Dept Quim Organ, E-28049 Madrid, Spain
来源：
CHEMICAL COMMUNICATIONS | 2011年 / 47卷 / 08期
关键词：
ENANTIOSELECTIVE 1,3-DIPOLAR CYCLOADDITION; MIXED PHOSPHORUS/SULFUR LIGANDS; STABILIZED SULFUR YLIDES; DIRECT MANNICH REACTION; AZOMETHINE YLIDES; ALLYLIC SUBSTITUTIONS; SULFONIUM SALTS; DERIVATIVES; MECHANISM; IMINES;
D O I：
10.1039/c0cc03978k
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Chiral, non-racemic, thioethers have provided organic chemists with useful tools for developing new reagents and catalysts for practical modern asymmetric synthesis. Disclosed herein is a brief personal overview on major recent contributions in this field in which the sulfur atom plays a leading role in the reaction pathway.
引用
收藏
页码：2207 / 2211
页数：5
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