Synthesis and decomposition of tri- and tetraoxide derivatives of dialkyl trisulfides

被引：4
|
作者：
Derbesy, G [1 ]
Harpp, DN [1 ]
机构：
[1] MCGILL UNIV,DEPT CHEM,MONTREAL,PQ H3A 2K6,CANADA
来源：
JOURNAL OF ORGANIC CHEMISTRY | 1996年 / 61卷 / 26期
关键词：
D O I：
10.1021/jo952244l
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
The first isolation and characterization of sulfinyl sulfonyl thioanhydride 1 and its tetrasulfide analog are presented here, along with those of disulfonyl thio- and dithioanhydrides 2. The oxidation of various substrates at different temperatures has shown that, contrary to current belief, oxidation takes place regiospecifically at the external sulfinyl sulfur rather than at the internal sulfenyl sulfur. The decomposition of these compounds has also been investigated and was found to be consistent with the mechanism proposed for the decomposition of trisulfide monoxides.
引用
收藏
页码：9471 / 9478
页数：8
相关论文
共 50 条
  • [41] New Phosphorus-Containing Quinone Derivatives II: Tri- and Tetraphosphorylated Quinone Derivatives
    Mueller, Patrick
    Fuhr, Olaf
    Doering, Manfred
    HETEROATOM CHEMISTRY, 2013, 24 (04) : 252 - 262
  • [42] New Spin Probes: Tri- and Hexacationic Derivatives of Stable Tetrathiatriarylmethyl Radicals
    Trukhin, D. V.
    Rogozhnikova, O. Yu.
    Troitskaya, T. I.
    Kuzhelev, A. A.
    Amosov, E. V.
    Halpern, H. J.
    Koval', V. V.
    Tormyshev, V. M.
    RUSSIAN JOURNAL OF ORGANIC CHEMISTRY, 2019, 55 (03) : 296 - 301
  • [43] New Spin Probes: Tri- and Hexacationic Derivatives of Stable Tetrathiatriarylmethyl Radicals
    D. V. Trukhin
    O. Yu. Rogozhnikova
    T. I. Troitskaya
    A. A. Kuzhelev
    E. V. Amosov
    H. J. Halpern
    V. V. Koval’
    V. M. Tormyshev
    Russian Journal of Organic Chemistry, 2019, 55 : 296 - 301
  • [44] FACILE SYNTHESIS OF DIALKYL FLUOROMALONATES AND THEIR DERIVATIVES
    ISHIKAWA, N
    TAKAOKA, A
    CHEMISTRY LETTERS, 1981, (01) : 107 - 110
  • [45] Regioselective nucleophilic substitution of the Baylis-Hillman adducts and synthesis of tri- and tetracyclic azepino-indole derivatives
    Shafiq, Zahid
    Liu, Li
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2018, 256
  • [46] Synthesis and characterization of homo-and heterobimetallic tri- and di-ethanolaminate derivatives containing dibutyltin(IV) moiety
    Sharma, K
    Sharma, M
    Singh, A
    Mehrotra, RC
    MAIN GROUP METAL CHEMISTRY, 2003, 26 (02): : 131 - 139
  • [47] Synthesis and mass spectrometry of some tri- and tetracyclic naphthenic acids
    Rowland, Steven J.
    Clough, Robert
    West, Charles E.
    Scarlett, Alan G.
    Jones, David
    Thompson, Samuel
    RAPID COMMUNICATIONS IN MASS SPECTROMETRY, 2011, 25 (17) : 2573 - 2578
  • [48] Synthesis of acyclic and macrocyclic analogs of Di-, Tri-, and tetranucleotides
    V. E. Semenov
    V. D. Akamsin
    V. S. Reznik
    Russian Journal of General Chemistry, 2007, 77 : 1430 - 1440
  • [49] Stereocontrolled Approach to Bromofluoroalkenes and Their Use for the Synthesis of Tri- and Tetrasubstituted Fluoroalkenes
    Landelle, Gregory
    Champagne, Pier Alexandre
    Barbeau, Xavier
    Paquin, Jean-Francois
    ORGANIC LETTERS, 2009, 11 (03) : 681 - 684
  • [50] Synthesis of acyclic and macrocyclic analogs of di-, tri-, and tetranucleotides
    Semenov, V. E.
    Akamsin, V. D.
    Reznik, V. S.
    RUSSIAN JOURNAL OF GENERAL CHEMISTRY, 2007, 77 (08) : 1430 - 1440
12345