Stereoselective total synthesis of (+)-sapinofuranone B

被引：19

作者：

Yadav, J. S. ^{[1
]}

Mandal, S. S. ^{[1
]}

Reddy, J. S. S. ^{[1
]}

Srihari, P. ^{[1
]}

机构：

[1] Indian Inst Chem Technol, Organ Div 1, CSIR, Hyderabad 500607, Andhra Pradesh, India

来源：

TETRAHEDRON | 2011年 / 67卷 / 25期

关键词：

GAMMA-LACTONE; ALKYNES; ACID;

D O I：

10.1016/j.tet.2011.04.072

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Two approaches for the total synthesis of (+)-sapinofuranone B have been described. The first strategy utilizes the methodology developed earlier in our group to get the chiral propargyl alcohol and the second strategy involves generation of threo-1,2-diol derivative by diastereoselective and enantioselective addition of [(Z)-gamma-methoxymethoxyallyl]diisopinocampheylborane onto aldehyde and cross metathesis as the key steps. (C) 2011 Elsevier Ltd. All rights reserved.

引用

页码：4620 / 4627

页数：8

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