Mathematical model of butadiene rubber synthesis over an organolithium catalytic system in a batch reactor

被引：0
|
作者：
Aminova, G. A. [1 ]
Manuiko, G. V. [1 ]
Garifullina, E. V. [1 ]
Bronskaya, V. V. [1 ]
Ignashina, T. V. [1 ]
Dyakonov, G. S. [1 ]
Ismagilova, A. I. [1 ]
机构：
[1] Kazan State Technol Univ, Kazan 420015, Tatarstan, Russia
来源：
THEORETICAL FOUNDATIONS OF CHEMICAL ENGINEERING | 2011年 / 45卷 / 04期
基金：
俄罗斯基础研究基金会;
关键词：
Butadiene; Batch Reactor; Chain Transfer; Conjugate Diene; Anionic Poly Merization;
D O I：
10.1134/S0040579511030031
中图分类号：
TQ [化学工业];
学科分类号：
0817 ;
摘要：
A mathematical model is proposed for butadiene rubber synthesis over an organolithium catalytic system in a batch reactor in the presence of a modifier and with adding toluene to a solvent. Using the developed model, the mechanism of the process is identified and the rate constants of the elementary stages are determined.
引用
收藏
页码：355 / 362
页数：8
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