Mathematical model of butadiene rubber synthesis over an organolithium catalytic system in a batch reactor

被引：0

作者：

Aminova, G. A. ^{[1
]}

Manuiko, G. V. ^{[1
]}

Garifullina, E. V. ^{[1
]}

Bronskaya, V. V. ^{[1
]}

Ignashina, T. V. ^{[1
]}

Dyakonov, G. S. ^{[1
]}

Ismagilova, A. I. ^{[1
]}

机构：

[1] Kazan State Technol Univ, Kazan 420015, Tatarstan, Russia

来源：

THEORETICAL FOUNDATIONS OF CHEMICAL ENGINEERING | 2011年 / 45卷 / 04期

基金：

俄罗斯基础研究基金会;

关键词：

Butadiene; Batch Reactor; Chain Transfer; Conjugate Diene; Anionic Poly Merization;

D O I：

10.1134/S0040579511030031

中图分类号：

TQ [化学工业];

学科分类号：

0817 ;

摘要：

A mathematical model is proposed for butadiene rubber synthesis over an organolithium catalytic system in a batch reactor in the presence of a modifier and with adding toluene to a solvent. Using the developed model, the mechanism of the process is identified and the rate constants of the elementary stages are determined.

引用

页码：355 / 362

页数：8

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