Vapour pressures at several temperatures, and excess functions at T = 298.15 K of (butanone plus 2-butanol)

被引:22
|
作者
Garriga, R [1 ]
Martínez, S [1 ]
Pérez, P [1 ]
Gracia, M [1 ]
机构
[1] Univ Zaragoza, Fac Ciencias, Dept Quim Organ Quim Fis Area Quim Fis, E-50009 Zaragoza, Spain
来源
JOURNAL OF CHEMICAL THERMODYNAMICS | 1999年 / 31卷 / 01期
关键词
excess functions; low pressure VLE; 2-butanol; butanone;
D O I
10.1006/jcht.1998.0432
中图分类号
O414.1 [热力学];
学科分类号
摘要
Vapour pressures of(butanone + 2-butanol) at eight temperatures between T = (278.15 and 323.15)K were measured by a static method. Excess enthalpies and volumes were also measured at T = 298.15 K. The reduction of the vapour pressures to obtain activity coefficients and excess molar Gibbs energies was carried out by fitting the vapour pressure data to the Redlich-Kister correlation according to Barker's method. The thermodynamic properties of the mixtures of alcohols in butanone and in n-hexane are compared with the available data and discussed. (C) 1999 Academic Press.
引用
收藏
页码:117 / 127
页数:11
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